Chemistry Ch 2 Heisenberg Flashcards

1
Q

Ap= uncertainty in momentum of particle

A
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2
Q

AVX = uncertainty in velocity of particle

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3
Q

Explanation : If the position of electron is

A
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4
Q

known (Ar is small)

A

then the velocity of the

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5
Q

electron will be uncertain in large.

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6
Q

IE the velocity of the electron is known

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7
Q

precisely

A

then the position of the electron will

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8
Q

be uncertain. Thus

A

if we carry out some

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9
Q

physical measurements of the electron’s

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10
Q

position or velocity

A

the outcome will always

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11
Q

depict a fuzzy or blur pictúre.

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12
Q

To decide position of electron : In order to

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13
Q

determine the position of an electron

A

we must-

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14
Q

use a meterstick calibrated in units of smaller

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15
Q

than the dimensions of electron.

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16
Q

To observe an electron

A

we can illuminate it

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17
Q

with “light” or electromagnetic radiation. The

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18
Q

“light” used must have a wavelength smaller

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19
Q

than the dimensions of an electron.

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20
Q

The high momentum photons of such light

21
Q

would change the energy of electrons

22
Q

by collisions. In this process we

23
Q

would be able to calculate the position of the

24
Q

electron

A

but we would know very little about

25
the velocity of the electron after the collision.
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Significance of uncertainty principle : One of
27
the important implications of the Heisenberg
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Uncertainty Principle is that it rules out
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existence of definite paths or trajectories of
30
electrons and other similar particles.
31
The trajectory of an object is determined by
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its location and velocity at various moments. If
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we know where a body is at a particular instant
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and if we also know its velocity and the forces
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acting on it at that instant
we can tell where
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the body would be sometime later.
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Since for a sub-atomic object such as an
38
electron
it is not possible simultaneously to
39
determine the position and velocity at any given
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Instant to an arbitrary degree of precision
it is
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not possible to talk of the trajectory of an
42
electron.
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Limitation: The effect of Heisenberg Uncertainty
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Principle is significant only for motion of
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microscopic objects and is negligible for that of
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macroscopic objects.
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# UID : P1-C2-S1-Q52
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