Chemistry Flashcards
_______________________ materials have unpaired electrons that align with magnetic fields, attracting the material to a magnet.
Paramagnetic
__________________________ materials have all paired electrons, which cannot easily be realigned and are repelled by magnets.
Diamagnetic
What is the equation for the Planck relation?
E = hf
What information about energy does the Planck relation provide us?
The energy of a quantum is directly proportional to its frequency as mediated by a constant, Planck’s constant (6.626 x 10-34 J·s)
What equation relates the energy of an electron to its principle quantum number (Bohr model)?
E = - RH/n2
What information about the energy of an electron does the Bohr model tell us?
The energy of an electron increases as the principle quantum number increases; although the equation seems to be an inverse relationship, the negative sign is critical - it means that we start from a more negative position and end at a less negative position, thereby increasing energy:
E = - RH/n2
What equation relates the energy of an electron to its frequency and wavelength?
E = hc/λ
What does the Planck relation using the wavelength of an electron tell us?
The energy of an electron is inversely proportional to its wavelength: higher wavelengths have lower energies and vice versa:
E = hc/λ
What equation explains the energy of an electron transition in the Bohr model?
E = -RH [1/ni2 - 1/nf2]
What does thie energy of an electron transition tell us about the relationship between an electron’s location and the energy released or emitted during a transition?
The energy of the emitted photon corresponds to the difference in energy between the higher-energy initial state and the lower-energy final state”
E = -RH [1/ni2 - 1/nf2]
Lyman
Balmer
Paschen series
The difference in energy between two shells decreases as the distance from the nucleus increases. This means that the energy difference between n = 3 and n =4 is _________ than that between n = 1 and n = 2.
Less
What is effective nuclear charge?
A measure of the net positive charge experienced by the outermost electrons
For elements in the same period or row, what trend occurs regarding effective nuclear charge (Zeff)?
It increases from left to right
_____________ ___________ is essentially opposite that of all other periodic trends. While others increase going up and to the right, ____________ ___________ increases going down and to the left.
Atomic radius
Atomic radius
Nonmetals ___________ to the metalloid line possess a larger ionic radius than their counterparts closer to the noble gases. However, metals __________ to the metalloid line possess a smaller ionic radius than their counterparts closer to the alkali metals.
Closer
Closer
_____________________ closer to the metalloid line possess a larger ionic radius than their counterparts closer to the noble gases. However, ______________ closer to the metalloid line possess a smaller ionic radius than their counterparts closer to the alkali metals.
Nonmetals
Metals
The Oxygen series is also known as what group?
The Chalogens
What explains the ability of transition metals to form colorful complexes with nonmetals in solution and their utility in certain biological systems?
They take on multiple oxidation states
_____________ are generally smaller than their corresponding neutral atom. ____________ are generally larger than their corresponding neutral atom.
Cations
Anions