Chemistry Flashcards

528

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1
Q

What does Hund’s rule state?

A

Hund’s rule states that electrons will fill degenerate orbitals or orbitals of identical energy with parallel spins before filling higher energy orbitals

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2
Q

Why do electrons remain unpaired?

A

Electrons remain unpaired to minimize electron-electron repulsion

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3
Q

What is the mass number of an atom?

A

The mass number of an atom is composed of protons and neutrons

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4
Q

How an you calculate the number of neutrons?

A

You subtract the atomic number of an atom (# of protons) from its atomic mass (# of protons and neutrons)

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5
Q

What is the electronegativity trend of the periodic table?

A

Upper right of the table is more electronegative

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6
Q

How do you describe electron affinity?

A

Electron affinity is the energy that is released when an atom in the gaseous state accepts an electron (ie. electron affinity is the energy released to form an anion)

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7
Q

How does the effective nuclear charge changes in respect to the periodic table?

A

Effective nuclear charge increases going from left to right as the number of protons in a nucleus increases

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8
Q

How does effective nuclear charge relate to atomic radius?

A

The higher the effective nuclear charge, while the electron density cloud stays the same across a period, electron cloud retracts, decreasing the atomic radius.

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9
Q

To what elements can hydrogen bonding occur with?

A

Hydrogen bonding can ocur with Flourine, Oxygen, or nitrogen.

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10
Q

Compare London dispersion forces with dipole dipole

A

Dipole dipole is when two polar bonds from two different molecules attract one another while London dispersion force is formed from the random shifts in electron density (momentary, easily broken)

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11
Q

What is a metathesis reaction?

A

A metathesis reaction is also known as a double displacement reaction

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12
Q

How do kinetics and temperature relate?

A

Whenever the temperature of a reaction increases so does the kinetics of that reaction.

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13
Q

What does the Arrhenius equation relate?

A

It relates the rate of a reaction to the temperature, activation energy, gas constant, and frequency factor, notable NOT enthalpy

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14
Q

What are the relation of matter and their amount of entropy?

A

Generally, gases have the greatest amount of entropy while solids have the smallest.

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15
Q

What is sublimation?

A

Sublimation is the change in phase from a solid to a gas

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16
Q

What equation can you use to determine if a reaction will be spontaneous or not?

A

DeltaG = Delta - TDeltaS related the conditions of a reaction and whether or not it would be spontaneous

17
Q

What is the relationship between delta G and spontaneity of a reaction?

A

When Delta G is negative, then a reaction is spontaneous

18
Q

What is the heat of formations of elements?

A

The heat of formation for elements is 0

19
Q

How do you calculate the standard enthalpy change?

A

You calculate the standard enthalpy change by Hess’s law which is the Hf of the products - the Hf of reactants

20
Q

What affects the speed of a gas particle?

A

The kinetic molecular theory of gases relate