chemistry Flashcards

To revise and understand

1
Q

BASIC BEHAVIOUR : Metal oxides and hydroxides

What ions accept bases and what are these ions referred to as?

A

Bases are substances that accept hydrogen ions, H+ and these iosn are referred to as proton receptors

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2
Q

Name two types of bases

A

Metal Oxides and Metal Hydroxides

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3
Q

Metal Oxides

What does oxide ions accept and what is an example of this??

A

Oxide ions in metal oxides accept protons and neutralise acids and an example is calcium oxide neutralises with sulfuric acid to form calcium sulpahte

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4
Q

What is calcium oxide used in and why is this important?

A

It is called lime and it is help to neutarlise acidic soils and this is important because when PH is too low, the plants tend to absorb toix ions and this hinders their root growth

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5
Q

Amphoteric acids

What is an amphoteric oxide?

A

An amphoteric oxide can behave as either a base or an acid depending pn what subatnce it is reacting with

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6
Q

Give an examples of amphoteric acids??

A
  • Aluminium Oxide
    -It doesn’t dissolve in water but when it reacts with an acid, it forms salt and water in a similar way to other metal oxides . Inwarm conditions it will react with HCL.
    -it will also react with bases to form aluminates . For instance it will react with NaOH to form ( sodium tetrahydroxoaluminate) which is used in the bayer process to convert mineral bauxite into aluminium oxide
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7
Q

Metal Hydroxides

what do metal oxides form when they react with water?

A

The reaction forms Hydroxides.

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8
Q

What does hydroxides ions accept?

A

They accept protons and neutalise acids

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9
Q

What is magnesium Hydroxide used for and what are the symptoms it helps relieves?

A
  • Magnesium Hydroxide is used as an antacid to relieve the symptoms of indigestion and heartburn by neutralising hydrochloric acid that has entered the oesophagus
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10
Q

what is calcium Hydroxide used for?

A
  • It is used to neutralise acidic effluent in the chemical industry i.e dilute solution od sulfuric acid in waste water from manufacturers of polymers
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11
Q

Aluminia

what is aluminia?

A
  • Aluminia is a form of aluminium oxide found in the mineral bauxite
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12
Q

what are properties of alumina??

A
  • it is an ionic compound
    -it has high melting point due to it’s strong ionic bonds.
  • It does not conduct electricity unless it is molten
    It is extracted and purified using the bayer process
    It is 8 times less the thermal conductivity of the normal aluminia
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13
Q

What is the stages of the bayer Process??

A
  • First bauxite is crushed
    -Then it reacts with Sodium hydroxide (aqueous state) at 170c to form sodium aluminium hydroxide
  • After this, the impurities formed are filtered out
    -This is then allowed to crytallise and form aluminium Hydroxide.
  • Lastly, this is heated in the rotary kiln to form (Al2o3)
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14
Q

what process is alumina used in and what does it form?

A
  • Alumina is used in the the Hall - Herlout process to form aluminum in electrolysis
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15
Q

What other material is alumina used in and why??

A
  • It is used in refractory material in Kilns and these materials retain their strength and a re chemically stable at high temperatures
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16
Q

Where are transition metals found in the periodic table?

A

They are found in the central block of the periodic table and they form stable ions with incomplete d-sub shell

17
Q

Why are Sc and Zn not classified as transition metals?

A
  • They are classified as d-block elements but not transition metals because their stable ions contain either a full or empty d-sub shell
18
Q

What are physical properties of transition metals

A
  • having a high melting point and boiling points
  • having high densities
    -are good conductors of heat and electricity
    -are stronger and harder than group 1 and 2 metals
19
Q

What are chemical properties of transition metals?

A
  • form coloured compounds
  • can exist in variable oxidation states
    -can behave as a catalyst
  • form coloured compounds that act as a catalyst
  • react with ligands to form complex ions
20
Q

What is a complex ion

A

Complex ions form when a ligand bonds to a metal ion using a dative covalent bond

21
Q

What is a ligand ?

A

A ligand is a species that has at least one lone pair of electrons that it can donate to the metal ion to form the dative covalent bonds to six water molecules

22
Q

What is an example of ligand and what is the name of this complex ion?

A
  • When copper sulphate dissolves in water , the copper ions break away from the sulphate ions and form dative covalent bonds to six water molecules and the name of this complex ion is ( hexaaquacopper (II) ion
23
Q

‘G.

24
Q

Transition Metals as catalyst

What are the two types of transition metals as catalyst called?

A

Heterogenous and Homogenous

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what do catalyst do?
They help speed up recations by providing alternate mechanisms for the reaction, thus lowering the activation energy.
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what is the Haber process used to do?
it is used to make ammonia from nitrogen and hydrogen
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# haber process what does this process require?
- it requires a tempertaure of 400*C to increase the rate of reaction - A pressure of 200 atm to increase the yield of product made - Nitrogen and Hydrogen need to be recycled - Hetergenous catalyst of iron that helps speed up the rate of reaction
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what is a homogenous catalyst?
- A homogenous catalyst is when the ctalayst is in the same physical state as the reactants
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what are key components of an homogenous catalyst?
-same state as reactants - speeds up the rate of reaction - is an intermediate reaction ( temporaily reacts with reactants to create a new substance, which breaks it down to give the final product which then causes it to regenerate) - catalyst can be reused as it is not fully used up
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# heterogenous catalyst what is a heterogenous catalyst?
- occurs in the haber process - Heterogenous catalyst is a iron catalyst that is in a different physical state (solid) to it's reactants (gas)
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what occurs during the process of heterogenous calatlyst?
- Reactants absorb the surface of the catalyst - causes bonds in reactants to weaken and thus causes a reaction to occur - products then desorb from the catalyst surface
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what is the contact process used for?
it is used to make sulfuric acid
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How is sulfur trioxide produced in the contact process?
- It uses vanadium oxide as a heterogenous catalyst in the reaction to form sulfur oxide
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How is sulfuric acid made?
- sulfur is burnt in oxygen to form sulfur dioxide in a fast reaction - then sulfur trioxide forms and then it is mixed with water to form sulfuric acid
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# Formulae in organic chemistry what are molecular formulas?? What are examples of molecular formulas?
- They tell you the number and type of atom that is within a molecule . It will give you no information as to how atoms are arranged within molecules . - butane C4H10, contains 4 carbon atoms and 10 hydrogen atoms
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what are structural formulas?
- They show how all atoms are arranges but it does not require all the bonds to be shown
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