chemistry Flashcards
To revise and understand
BASIC BEHAVIOUR : Metal oxides and hydroxides
What ions accept bases and what are these ions referred to as?
Bases are substances that accept hydrogen ions, H+ and these iosn are referred to as proton receptors
Name two types of bases
Metal Oxides and Metal Hydroxides
Metal Oxides
What does oxide ions accept and what is an example of this??
Oxide ions in metal oxides accept protons and neutralise acids and an example is calcium oxide neutralises with sulfuric acid to form calcium sulpahte
What is calcium oxide used in and why is this important?
It is called lime and it is help to neutarlise acidic soils and this is important because when PH is too low, the plants tend to absorb toix ions and this hinders their root growth
Amphoteric acids
What is an amphoteric oxide?
An amphoteric oxide can behave as either a base or an acid depending pn what subatnce it is reacting with
Give an examples of amphoteric acids??
- Aluminium Oxide
-It doesn’t dissolve in water but when it reacts with an acid, it forms salt and water in a similar way to other metal oxides . Inwarm conditions it will react with HCL.
-it will also react with bases to form aluminates . For instance it will react with NaOH to form ( sodium tetrahydroxoaluminate) which is used in the bayer process to convert mineral bauxite into aluminium oxide
Metal Hydroxides
what do metal oxides form when they react with water?
The reaction forms Hydroxides.
What does hydroxides ions accept?
They accept protons and neutalise acids
What is magnesium Hydroxide used for and what are the symptoms it helps relieves?
- Magnesium Hydroxide is used as an antacid to relieve the symptoms of indigestion and heartburn by neutralising hydrochloric acid that has entered the oesophagus
what is calcium Hydroxide used for?
- It is used to neutralise acidic effluent in the chemical industry i.e dilute solution od sulfuric acid in waste water from manufacturers of polymers
Aluminia
what is aluminia?
- Aluminia is a form of aluminium oxide found in the mineral bauxite
what are properties of alumina??
- it is an ionic compound
-it has high melting point due to it’s strong ionic bonds. - It does not conduct electricity unless it is molten
It is extracted and purified using the bayer process
It is 8 times less the thermal conductivity of the normal aluminia
What is the stages of the bayer Process??
- First bauxite is crushed
-Then it reacts with Sodium hydroxide (aqueous state) at 170c to form sodium aluminium hydroxide - After this, the impurities formed are filtered out
-This is then allowed to crytallise and form aluminium Hydroxide. - Lastly, this is heated in the rotary kiln to form (Al2o3)
what process is alumina used in and what does it form?
- Alumina is used in the the Hall - Herlout process to form aluminum in electrolysis
What other material is alumina used in and why??
- It is used in refractory material in Kilns and these materials retain their strength and a re chemically stable at high temperatures
Where are transition metals found in the periodic table?
They are found in the central block of the periodic table and they form stable ions with incomplete d-sub shell
Why are Sc and Zn not classified as transition metals?
- They are classified as d-block elements but not transition metals because their stable ions contain either a full or empty d-sub shell
What are physical properties of transition metals
- having a high melting point and boiling points
- having high densities
-are good conductors of heat and electricity
-are stronger and harder than group 1 and 2 metals
What are chemical properties of transition metals?
- form coloured compounds
- can exist in variable oxidation states
-can behave as a catalyst - form coloured compounds that act as a catalyst
- react with ligands to form complex ions
What is a complex ion
Complex ions form when a ligand bonds to a metal ion using a dative covalent bond
What is a ligand ?
A ligand is a species that has at least one lone pair of electrons that it can donate to the metal ion to form the dative covalent bonds to six water molecules
What is an example of ligand and what is the name of this complex ion?
- When copper sulphate dissolves in water , the copper ions break away from the sulphate ions and form dative covalent bonds to six water molecules and the name of this complex ion is ( hexaaquacopper (II) ion
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Transition Metals as catalyst
What are the two types of transition metals as catalyst called?
Heterogenous and Homogenous