Chemistry Flashcards

Distinction

1
Q

Electron configuration

A

refers to the distribution of electrons among the orbitals of an atom.

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2
Q

Electrons filling orbitals

A

in order of increasing energy, starting from the lowest energy orbital (1s) and moving upwards. This is based on the Aufbau Principle.

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3
Q

Electron filling orbital sequence

A

1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p, 6s, 4f, 5d, 6p

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4
Q

Hund’s Rule

A

Electrons will occupy empty orbitals of the same energy (degenerate orbitals) singly before pairing up.

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5
Q

Pauli Exclusion Principle

A

No two electrons can have the same set of quantum numbers, so an orbital can hold a maximum of two electrons with opposite spins.

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6
Q

Electron Configurations for Elements

A

Use the atomic number to determine how many electrons an atom has, and then distribute them according to the orbital filling order.

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7
Q

Determine the Position of an Element in the Periodic Table from its Electronic Structure - Group Number

A

The group number corresponds to the number of electrons in the outermost shell.

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8
Q

Determine the Position of an Element in the Periodic Table from its Electronic Structure - Period

A

The period corresponds to the highest energy level (principal quantum number, n) that contains electrons.

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9
Q

Sodium (Na): 1s² 2s² 2p⁶ 3s¹

Period and Group -

A

Group 1 (1 electron in the outermost s orbital).
Period 3 (highest principal quantum number is 3).

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10
Q

Blocks of the Periodic Table:
Elements are divided into blocks based on their electron configuration

A

d-block: Transition metals
S-Block
P-block

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11
Q

Transition Metals

A

Transition metals have partially filled d orbitals, and their electron configurations typically end in d orbitals

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12
Q

Ion Formation
Ions -

A

Ions form when atoms lose or gain electrons to achieve a full outer shell (usually achieving the same electron configuration as a noble gas).

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13
Q

ions formation
metal -

A

lose electrons to form positive ions (cations)

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14
Q

Non-metals

A

gain electrons to form negative ions (anions).

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15
Q

Examples of Ion formation

A

Sodium (Na): Loses 1 electron to form Na⁺.
Configuration: Na⁺ = 1s² 2s² 2p⁶ (same as Neon).
Chlorine (Cl): Gains 1 electron to form Cl⁻.
Configuration: Cl⁻ = 1s² 2s² 2p⁶ 3s² 3p⁶ (same as Argon).

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16
Q

Formulae of Ionic Compounds
Combine cations and anions to form neutral compounds.

A

Sodium Chloride (NaCl):
Na⁺ and Cl⁻ combine to form NaCl (ionic bond).
Calcium Oxide (CaO):
Ca²⁺ and O²⁻ combine to form CaO.

17
Q

Ionic Bonding

A

Occurs between metals and non-metals.
Involves the transfer of electrons from a metal to a non-metal, forming positive and negative ions

18
Q

Ionic Bonding properties

A

High melting and boiling points.
Conduct electricity when dissolved in water (as ions are free to move).
Brittle.

19
Q

Covalent Bonding

A

Occurs between non-metals.
Involves the sharing of electron pairs between atoms.

20
Q

Covalent Bonding Properties

A

Lower melting and boiling points compared to ionic compounds.
Do not conduct electricity.

21
Q

Metallic Bonding

A

Occurs in metals.
Delocalized electrons (free electrons) move throughout the lattice of metal cations.

22
Q

Metallic Bonding Properties

A

Conduct electricity.
Malleable and ductile.

23
Q

Intermolecular Forces

A

These are forces between molecules (not within molecules)

24
Q

Van der Waals Forces

A

Weak interactions between non-polar molecules.
Example: Between O₂ molecules.

25
Q

Hydrogen Bonding

A

Stronger than Van der Waals, occurs when hydrogen is bonded to electronegative atoms (N, O, F).
Example: Between H₂O molecules (responsible for water’s high boiling point).

26
Q

Prediction of Bonding Types

A

Ionic: Typically formed between metals and non-metals.
Covalent: Typically formed between two non-metals.
Metallic: Found in pure metals and alloys.
Intermolecular Forces: Found between molecules with covalent bonds.