chemical spectroscopy Flashcards
deals with the interaction of light with chemical substances
chemical spectroscopy
only one part of the electromagnetic spectrum made of electromagnetic wave
light/visible light
parts pf light
- electric field component
2, magnetic field component
a disturbance that transmit energy
wave
speed of light
3.0 × 10⁵ m/s
speed of light =
wavelength × frequency
wave energy =
planck’s constant × frequency
electromagnetic spectrum (from lowest to highest)
- radio waves
- microwaves
- infrared
- visible light
- ultraviolet
- X-rays
- Gamma rays
type of quantum change in IR
change in configuration: bending, stretching, and scissoring
type of quantum change in UV-VIS
change in electron configuration: molecular and atomic
spectroscopic measurements
emission and absorption
sample is exited by applying heat or electricity
emission
when electrons return to ground state, they emit radiation characteristics of a given atom
emission
measures the light absorbed as a function of wavelength
absorption
components of various types of optical spectroscopy
- source
- wavelength selector
- sample container
- radiation detector
- signal processing and read out unit
isolates the desired wavelength band so that the only the band of interest is detected and measured
monochromator
types of monochromator
- grating
- prism
monochromator with 100-40,000 nm range
grating monochromator
monochromator with 120-30,000 nm range
prism monochromator
detector
phototubes
works via photoelectric effect
phototubes
UV-Vis spectrometer
source > monochromator >< shutter >< sample (blank) > detector> signal processor
instrument components
- source
- monochromator (entrance slit, dispersion device, and exit slit)
- sample
- detector
two ways of expressing amount of light
- transmittance
- absorbance