chemical spectroscopy Flashcards

1
Q

deals with the interaction of light with chemical substances

A

chemical spectroscopy

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2
Q

only one part of the electromagnetic spectrum made of electromagnetic wave

A

light/visible light

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3
Q

parts pf light

A
  1. electric field component
    2, magnetic field component
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4
Q

a disturbance that transmit energy

A

wave

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5
Q

speed of light

A

3.0 × 10⁵ m/s

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6
Q

speed of light =

A

wavelength × frequency

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7
Q

wave energy =

A

planck’s constant × frequency

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8
Q

electromagnetic spectrum (from lowest to highest)

A
  1. radio waves
  2. microwaves
  3. infrared
  4. visible light
  5. ultraviolet
  6. X-rays
  7. Gamma rays
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9
Q

type of quantum change in IR

A

change in configuration: bending, stretching, and scissoring

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10
Q

type of quantum change in UV-VIS

A

change in electron configuration: molecular and atomic

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11
Q

spectroscopic measurements

A

emission and absorption

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12
Q

sample is exited by applying heat or electricity

A

emission

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13
Q

when electrons return to ground state, they emit radiation characteristics of a given atom

A

emission

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14
Q

measures the light absorbed as a function of wavelength

A

absorption

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15
Q

components of various types of optical spectroscopy

A
  1. source
  2. wavelength selector
  3. sample container
  4. radiation detector
  5. signal processing and read out unit
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16
Q

isolates the desired wavelength band so that the only the band of interest is detected and measured

A

monochromator

17
Q

types of monochromator

A
  1. grating
  2. prism
18
Q

monochromator with 100-40,000 nm range

A

grating monochromator

19
Q

monochromator with 120-30,000 nm range

A

prism monochromator

20
Q

detector

A

phototubes

21
Q

works via photoelectric effect

A

phototubes

22
Q

UV-Vis spectrometer

A

source > monochromator >< shutter >< sample (blank) > detector> signal processor

23
Q

instrument components

A
  1. source
  2. monochromator (entrance slit, dispersion device, and exit slit)
  3. sample
  4. detector
24
Q

two ways of expressing amount of light

A
  1. transmittance
  2. absorbance
25
human eye serves as the detector
colorimeter
26
use a absorption or interference filters for wavelength selection and a photoelectric device for measuring radiant power
photometer
27
uses a monochromator or a polychromator in conjunction with a transducer to convert the radiant intensities into electrical signals
spectrometers
28
special type of spectrometer in which wavelength can be varied continuously, thus making scanning of absorption spectra possible
spectrophotometers
29
one of the most useful techniques in investigating the structure of organic compounds
Infrared spectroscopy
30
used as a tool for qualitative and quantitative determination of molecular species
infrared spectroscopy
31
energy of IR photon insufficient to cause electronic excitation but can cause vibrational or rotational excitation
infrared absorption