chemical spectroscopy Flashcards

1
Q

deals with the interaction of light with chemical substances

A

chemical spectroscopy

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2
Q

only one part of the electromagnetic spectrum made of electromagnetic wave

A

light/visible light

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3
Q

parts pf light

A
  1. electric field component
    2, magnetic field component
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4
Q

a disturbance that transmit energy

A

wave

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5
Q

speed of light

A

3.0 × 10⁵ m/s

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6
Q

speed of light =

A

wavelength × frequency

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7
Q

wave energy =

A

planck’s constant × frequency

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8
Q

electromagnetic spectrum (from lowest to highest)

A
  1. radio waves
  2. microwaves
  3. infrared
  4. visible light
  5. ultraviolet
  6. X-rays
  7. Gamma rays
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9
Q

type of quantum change in IR

A

change in configuration: bending, stretching, and scissoring

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10
Q

type of quantum change in UV-VIS

A

change in electron configuration: molecular and atomic

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11
Q

spectroscopic measurements

A

emission and absorption

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12
Q

sample is exited by applying heat or electricity

A

emission

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13
Q

when electrons return to ground state, they emit radiation characteristics of a given atom

A

emission

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14
Q

measures the light absorbed as a function of wavelength

A

absorption

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15
Q

components of various types of optical spectroscopy

A
  1. source
  2. wavelength selector
  3. sample container
  4. radiation detector
  5. signal processing and read out unit
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16
Q

isolates the desired wavelength band so that the only the band of interest is detected and measured

A

monochromator

17
Q

types of monochromator

A
  1. grating
  2. prism
18
Q

monochromator with 100-40,000 nm range

A

grating monochromator

19
Q

monochromator with 120-30,000 nm range

A

prism monochromator

20
Q

detector

A

phototubes

21
Q

works via photoelectric effect

A

phototubes

22
Q

UV-Vis spectrometer

A

source > monochromator >< shutter >< sample (blank) > detector> signal processor

23
Q

instrument components

A
  1. source
  2. monochromator (entrance slit, dispersion device, and exit slit)
  3. sample
  4. detector
24
Q

two ways of expressing amount of light

A
  1. transmittance
  2. absorbance
25
Q

human eye serves as the detector

A

colorimeter

26
Q

use a absorption or interference filters for wavelength selection and a photoelectric device for measuring radiant power

A

photometer

27
Q

uses a monochromator or a polychromator in conjunction with a transducer to convert the radiant intensities into electrical signals

A

spectrometers

28
Q

special type of spectrometer in which wavelength can be varied continuously, thus making scanning of absorption spectra possible

A

spectrophotometers

29
Q

one of the most useful techniques in investigating the structure of organic compounds

A

Infrared spectroscopy

30
Q

used as a tool for qualitative and quantitative determination of molecular species

A

infrared spectroscopy

31
Q

energy of IR photon insufficient to cause electronic excitation but can cause vibrational or rotational excitation

A

infrared absorption