Chemical reactions Flashcards
Acid base reaction
Transfer of proton from acid to base
Acid + metal hydroxide (or oxide)
Metal salt and water
Acid + metal carbonate
Metal salt + CO2 + H2O
Acid + metal sulfide
Metal salt + hydrogen sulfide (H2S)
Eg. 2HCl + FeS —> FeCl2 + H2S
Reduction and oxidation define
OIL RIG
oxidation is loss
Reduction is gain (of electrons)
Oxidation = lose e, gain Ox, ox no increase, remove H
Red = gain e, lose Ox, ox no decrease, gain H
Reactive metal and water
—> metal HYDROXIDE and H2
Eg Ca + H2O —> Ca(OH)2 + H2
In G2, only Mg makes Oxide + H2
Metal and oxygen
Metal oxide
Heat a metal carbonate
Thermal decomposition into metal OXIDE and CO2
Heat metal hydrogen carbonate G1 and G2
Thermal decomposition
G1 Metal CARBONATE + CO2 + H2O
G2 metal OXIDE + CO2
Heat metal hydroxide
Metal OXIDE and H2O
Alkali metals stable to heat
Common oxidants are…
Oxygen and non-metals
oxygen to oxide ion
Iodine, chlorine to ion
Hydrogen peroxide to water
Permanganate to manganese
Dichromate your chromium
Common reductants
Hydrogen and metals
Metal to metal ion
Carbon to carbon dioxide
Hydrogen to water
Sulfite to sulfate (gain ox)
More reactive metal, the better the reductant
Reduction half equation permanganate
MnO4- + 8H+ + 5e- —> Mn2+ + 4 H2O
5 electrons
Dichromate reduction half equatio
(Cr2O7)2- + 14H+ + 6e- —> 2Cr3+ + 7H2O
6 electrons
Disproportionation
Can oxidise and reduce itself
A redox reaction in which the same element is both oxidised and reduced
Eg hydrogen peroxide (ON -1)
H2O2 to O2 (ON 0, oxidised, reductant)
H2O2 to H2O (ON -2, reduced, oxidant)