Chemical reactions Flashcards

1
Q

Acid base reaction

A

Transfer of proton from acid to base

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2
Q

Acid + metal hydroxide (or oxide)

A

Metal salt and water

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3
Q

Acid + metal carbonate

A

Metal salt + CO2 + H2O

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4
Q

Acid + metal sulfide

A

Metal salt + hydrogen sulfide (H2S)

Eg. 2HCl + FeS —> FeCl2 + H2S

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5
Q

Reduction and oxidation define

A

OIL RIG
oxidation is loss
Reduction is gain (of electrons)

Oxidation = lose e, gain Ox, ox no increase, remove H

Red = gain e, lose Ox, ox no decrease, gain H

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6
Q

Reactive metal and water

A

—> metal HYDROXIDE and H2

Eg Ca + H2O —> Ca(OH)2 + H2

In G2, only Mg makes Oxide + H2

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7
Q

Metal and oxygen

A

Metal oxide

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8
Q

Heat a metal carbonate

A

Thermal decomposition into metal OXIDE and CO2

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9
Q

Heat metal hydrogen carbonate G1 and G2

A

Thermal decomposition

G1 Metal CARBONATE + CO2 + H2O
G2 metal OXIDE + CO2

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10
Q

Heat metal hydroxide

A

Metal OXIDE and H2O

Alkali metals stable to heat

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11
Q

Common oxidants are…

A

Oxygen and non-metals

oxygen to oxide ion

Iodine, chlorine to ion

Hydrogen peroxide to water

Permanganate to manganese

Dichromate your chromium

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12
Q

Common reductants

A

Hydrogen and metals

Metal to metal ion

Carbon to carbon dioxide

Hydrogen to water

Sulfite to sulfate (gain ox)

More reactive metal, the better the reductant

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13
Q

Reduction half equation permanganate

A

MnO4- + 8H+ + 5e- —> Mn2+ + 4 H2O

5 electrons

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14
Q

Dichromate reduction half equatio

A

(Cr2O7)2- + 14H+ + 6e- —> 2Cr3+ + 7H2O

6 electrons

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15
Q

Disproportionation

A

Can oxidise and reduce itself

A redox reaction in which the same element is both oxidised and reduced

Eg hydrogen peroxide (ON -1)

H2O2 to O2 (ON 0, oxidised, reductant)

H2O2 to H2O (ON -2, reduced, oxidant)

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16
Q

Warm an alkali metal hydroxide and ammonium salt

A

Metal salt + ammonia + water

17
Q

Metal oxide and water

A

Metal hydroxide

Only GI and GII

18
Q

Oxidation number of an element

A

0

19
Q

Oxidation numbers in a molecule

A

Add to 0

20
Q

Oxidation numbers in an ion

A

Oxidation number is the charge of the ion

21
Q

Ox number in polyatomic ion

A

Add to the charge of the ion

22
Q

Oxidation number of oxygen

A

Always -2 EXCEPT in peroxides

Eg. H2O2
Where it is -1

23
Q

Ox number H in compounds

A

Always +1
(With more electroneg, non metals)
In metal hydrides Eg. NaH
M it is -1

24
Q

The oxidation of F in compounds

A

Always -1

25
Q

NO2 gas colour

A

Brown

26
Q

Metal nitrite + water

A

Metal hydroxide + NH3

27
Q

Spontaneous reaction define

A

A reaction that favours the formation of products at the conditions under which the reaction is occurring
IN TERMS OF ENTHALPY??

28
Q

4 common STRONG acids

A

HCl
HNO3
H2SO4
HBr

29
Q

3 common weak acids

A

HF
HCOOH
CH3COOH

30
Q

strong bases formula

A

OH is in the formula

eg. NaOH –> Na+ + OH-
do not need H2O as a reactant

31
Q

Weak bases

A

OH not in formula, needs water as a reactant.

eg. ammonia NH3 + H2O = NH4+ + OH-

methanamine CH2NH2 + H2O = CH3NH3+ + OH-

32
Q

acidic/basic salts

A

dissociate first. Carboxylic salts, metal carbonates, ammonium salts (AMMONIUM ion is the one that further reacts with water)

NaCH3COO –> Na+ + CH3COO-
CH3COO- + H2O = CH3COOH + OH-

Na2CO3 –> 2Na+ + CO3(2-)
CO3(2-) + H2O = OH- + HCO3-