chemical process safety Flashcards

1
Q

Which of the following is not measure
of effectiveness safety program?

A

HAZOP

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

How toxicants enters into organism?

A

Ingestion, Injection, Inhalation

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

Lowest value on response vs dose
curve is called

A

Thresold Limit Value

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Identification, Evaluation and control
are the phases of

A

Industrial Hygiene

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

Fire is rapid——– of ignited fuel

A

Exothermic oxidation

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

………………..is a rapid increase in
volume and release of energy in an
extreme manner, usually with the
generation of high temperatures and
the release of gases

A

Explosion

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

…………..is the lowest temperature
that the vapours of a material will
ignite when exposed to an ignition
source.

A

Fire point

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

An explosion occurring within a vessel
or a building, known as

A

Confined Explosion

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

Which of the following Causes of
overpressure…..

A

Ambient heat, Valve failures

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

For material handling which is wrong
statement………

A

Environmental risk
assessments should
not be available.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

Who is responsible for ensuring the
workers are provided with safe
working environment?

A

OSHA

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

Hazard evaluation consist of the
elements…..

A

Safety Review/Audit/Inspection, HAZAN, HAZOP

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Which of the following is not Guide word of HAZOP?

A

NAND

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

Process of adding inert gas to combustible mixture
to reduce concentration of oxygen below limiting oxygen concentration (LOC

A

inerting

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

Vessels can be pressure-purged by
adding inert gas ………

A

Under atmospheric
pressure

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

The ____________ process
determines whether exposure to a
chemical can increase the incidence
of adverse health effect.

A

Hazard identification

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
17
Q

Hazard is defined as the probability of

A

suffering harm or loss

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
18
Q

……….. occurs when a tank
containing a liquid held above its
atmospheric pressure boiling point
ruptures, resulting in the explosive
vaporization of a large fraction of the
tank contents.

A

Boiling-Liquid
Expanding-Vapor
Explosion

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
19
Q

for……… the reaction front
propagates at a speed less than the
speed of sound

A

deflagration

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
20
Q

Static electricity is generated when

A

mists or sprays pass
through orifices

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
21
Q

The MIE depends on the

A

specific chemical or mixture, concentration. pressure and temperature

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
22
Q

An explosion resulting from the
sudden failure of a vessel containing
high-pressure nonreactive gas

A

Mechanical explosion

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
23
Q

The essential elements for
……………… are fuel, an oxidizer,
and an ignition source

A

Fire triangle

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
24
Q

What is toxicity equivalence factor?

A

Ratio of the toxicity of
a chemical to that of
another structurally
related chemical (or
index compound)
chosen as a reference

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
25
OSHA ensures that employees have been provided with
PPE
26
ED stands for
Effective dose
27
Eco-toxicology is based on ______ of chemicals.
Toxicological
28
During the ……………...phase, the various types of existing control measures and their effectiveness are also studied.
Evaluation
29
The unit-specific technical requirements are designed to ……
Prevent the release of HW
30
What are the steps involved in evaluation of toxicity?
hazard identification and dose-response evaluation
31
establishes the relationship between the contaminant/s of concern and the receptor.
Toxicity assessment
32
Which of the following is not characteristics of hazardous waste?
Leakage
33
Results from long-term exposure to lower doses of a chemical is known as ________
Chronic toxicity
34
Which of the following chemical is responsible for acute lung disease from Bhopal gas tragedy?
Methylisocyanate
35
Heavy metals like Arsenic, Cadmium and Cyanide effects _________
Nervous system
36
______ represents a contact between a chemical agent and an object.
Exposure
37
Under the OSH Act, employers are responsible for providing a
Safe workplace
38
OSHA was created to _________
To reduce hazards
39
How is sensitivity analysed in risk estimation?
By critical assumptions
40
An incident can be called hazardous only when?
Stressor has the potential to cause harm to humans and ecological systems
41
What is the main purpose of hazard identification?
To characterize adverse effect of toxins
42
Doses are expressed on a _________ basis.
Body-weight
43
Major application of dose-response curve is to obtain ______
Threshold
44
Which of the following valve is known as a safety valve?
Pressure relief valve
45
When did Seveso accident occur?
1976
46
A waste to be called toxic, acute oral LD50 concentration should be _______ mg/kg.
2500
47
What is chronic toxicity?
Effects due to long term exposure
48
The gauge pressure during normal service, usually 10% below the MAWP known as
Operating pressure
49
Pressure relief systems are required for which of the following reasons
to protect personnel from the dangers of overpressurizing equipment, to minimize chemical losses during pressure upsets,
50
Why does site history have to be considered for hazard identification?
To know the probable source and causes of contamination on site
51
Hazard identification mainly focus on
Chemical source and concentration
52
Estimation of short-term and long term exposure are usually in terms of
Doses by exposure rate
53
Which of the following risk assessment tool is used for the determination of spatial distribution of contaminants at the site?
Exposure assessment
54
What is the final stage of risk assessment?
Risk characterisation
55
The toxicological end point for dose- response relationship should be _________
Definitive
56
For existing chemicals, we should always consider ________ exposure assessment based on modelling, to derive an environmental concentration.
Reasonable worst case
57
What is the main goal of risk management?
Calculate probability of adverse effect on individual and population
58
Elements of safe chemical storage program consist of
Inventory of Chemicals, labelling of chemicals, segregating incompatibles
59
The FAR reports the number of fatalities based on 1000 employees working their entire lifetime. The employees are assumed to work a total of 50 years.
FAR
60
The last step of accident process
Termination
61
LD50 in a toxicity test stands for ______
a dose that will kill 50% of an exposed population
62
The pressure difference between the relief set pressure and the relief reseating pressure. It is expressed as a percentage of the set pressure.
Blowdown
63
What is the most common approach used to asses skin exposure to a contaminant?
using pad or dosimeters to determine the amount of contaminant deposited on the skin
64
this American federal act was the first know legal adoption of standards for allowable concentrations of chemicals in workplace air
Walsh-healey Public Contract Act
65
The most well known OEls are established by
ACGIH
66
The ACGIH TLVs
are science based
67
If three of the following are said to be exposure limits for chemical X, which one is likely to be the ceiling limit
1000ppm
68
The definition of the ACGIH TLV_STELs refer to certain health effects that must be avoided. these do not include
carcinogenicity
69
Which organization is widely recognized around the world as setting exposure limits for ionizing radiation
International commission on Radiological Protection (ICRP)
70
Which is not an agent ACGIH sets standards for
ionizing radiation
71
Which is not one of the main forms in which chemicals are present in the workplace
fibers
72
Chemical scause two main kinds of health effects
local effects and poisoning
73
Who said it is the dose only that makes a thing not a poison
Paracelsus
74
a dose response curve illustrating acute toxicity usually has
a s-shaped or sigmoidal curve
75
If the dose response curves of three chemicals are shown on the same graph, the one which intersects the x- axis (dose) at the lowest dose is
the most poisonous
76
the most common type of LD 50 test involves
an oral dose
77
For any given chemical, a high LD 50 value generally means
low toxicity
78
Which statement about ingestion as a route of entry into the workers body by workplace chemicals is incorrect
ingestion is usually a significant way in which chemicals gain entry into the body
79
the two main categories of skin irritation caused by chemicals are
inflammation and corrosion
80
An example of a workplace chemical that can damage the kidneys specifically is
lead salts
81
Which is not a chemical known to specifically damage the kidney
vinyl chloride
82
Which is not one of the four main types of skin exposures
radiological
83
What violations are most commonly cited by OSHA?
Fall protection
84
What is the leading cause of death on construction sites?
Falls
85
Which of the following is not a chemical-related health hazard?
Reactivity
86
Rubber insulating gloves need to be tested:
Before first use and then every 6 months
87
Which of the following is not measure of effectiveness safety program?
HAZOP
88
Lowest value on response vs dose curve is called…
Thresold Limit Value
89
Identification, Evaluation and control are the phases of…….
Industrial Hygiene
90
Fire is rapid-------- of ignited fuel.
Exothermic oxidation
91
………………..is a rapid increase in volume and release of energy in an extreme manner, usually with the generation of high temperatures and the release of gases
Explosion
92
…………..is the lowest temperature that the vapours of a material will ignite when exposed to an ignition source.
Fire point
93
During the ……………...phase, the various types of existing control measures and their effectiveness are also studied.
Evaluation
94
Why does site history have to be considered for hazard identification?
To know the probable source and causes of contamination on site
95
Hazard identification mainly focus on
Chemical source and concentration
96
Estimation of short-term and long term exposure are usually in terms of
Doses by exposure rate
97
Which of the following risk assessment tool is used for the determination of spatial distribution of contaminants at the site?
Exposure assessment
98
What is the final stage of risk assessment?
Risk characterisation
99
The toxicological end point for dose- response relationship should be _________
Definitive
100
For existing chemicals, we should always consider ________ exposure assessment based on modelling, to derive an environmental concentration.
Reasonable worst case
101
What is the main goal of risk management?
Calculate probability of adverse effect on individual and population
102
Each chemical family is to be separated by
Non-combustible partition
103
Which of the following should not be stored near organic acids
Oxidizing mineral acids
104
Which of the following to be referred during storage of specific chemicals
Chemical Storage Guide
105
Acetic acid is both
Corrosive acid and combustible liquid
106
Flammable and combustible liquids are to stored in
Flammable storage cabinets
107
Inerting is the process of adding an inert gas to a combustible mixture to reduce the
Least Oxygen Concentration
108
The _____________ purging process adds purge gas into a vessel at one opening and withdraws the mixed gas from the vessel to the atmosphere (or scrubber) from
Sweep-through
109
When charged liquid droplets or solid particles settle on an isolated object, the object is charged then it is a
Charging by transport
110
is applicable only to materials that are electrically conductive
Induction charging
111
Spark Discharge is a discharge between two
Metallic objects
112
A _________ is a discharge from a grounded conductor when it approaches a charged insulator that is backed by a conductor
Propagating brush discharge
113
The purpose of ventilation is to dilute the _______ with air to prevent explosion and to confine the ______ mixtures.
Explosive vapors; hazardous flammable
114
While storing of chemicals in store rooms the care must be taken for the leaks, spills and
drips
115
Prevent chemicals from running down sink, floor, or
Storm water drains
116
An inerting system is required to maintain an inert atmosphere in the _______ above the liquid.
Vapour space
117
vacuum purging is a common procedure for which of the following
reactors
118
vessel is pressurized with pure nitrogen, the number of moles of oxygen________ during pressurization, whereas the mole fraction
Remains constant; decreases
119
In _________ Purging results are defined by assuming perfect mixing within the vessel, constant temperature, and constant pressure.
sweep-through purging
120
The _______ process requires large quantities of nitrogen
sweep-through purging
121
The _________ process starts by filling the vessel with liquid - water or any liquid Compatible with the product.
Siphon purging
122
In ____ purging the oxygen concentration is decreased to low concentrations
Siphon purging
123
During equipment design for unavoidable ________ design features are added to continuously and reliably inert the atmosphere around the regions where static sparks are likely.
Static build-up
124
Static charge build-up is a result of physically separating a _____ from a good conductor or another poor conductor.
Poor conductor
125
The following is indirect cost of accident
Cost of lost time of injured worker
126
Check list for Job Safety Analysis (JSA) consists of
Work area, material, machine, tools
127
safety programme consists of
Four E’s
128
Which of the following colour is used for radiation hazard?
Purple
129
Decibel (db) is a unit used to measure
sound
130
Class-A fire consists of fire due to
wood
131
Water is used to extinguish
Class-A fires
132
The following class of fire occur in electrical equipment
Class-C fires
133
The following extinguisher is suitable for cotton or other textile fire
Dry chemicals
134
is best suited to extinguishing oil or flammable liquid fire.
Foam