Chemical Kinetics Flashcards
collision theory
- for chemical reaction to occur:
- reactants must collide
- in correct orientation
- w/ sufficient KE (above Ea)
activation E
E required for reactants to form products (Ea)
rate of reaction
- increase in product conc over unit time
- decrease in reactant conc over unit time
ΔH
diff. betw system E and E of system when products = formed
what affects rate of reaction?
- temp
- catalyst
- conc
- SA
how does temp affect rate of reaction?
> temp. = > KE of particles = > frequency of collisions = > no. successful collisions = faster reaction
how does the presence of a catalyst affect rate of reaction?
-may provide alternative pathway w/ lower Ea, increasing probability of proper orientation = > frequency of successful collisions = faster reaction
how does concentration affect rate of reaction?
-higher conc = more frequent collisions = faster reaction
how does SA affect rate of reaction?
-smaller solid particles cause faster reaction bc surface = where reaction occurs