Chemical Kinematics Flashcards

1
Q

Rate of a Reaction

A

– defined as the change in the
concentration of reactants or products per change in
time.

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2
Q

Rate=

A
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3
Q

Rate Law

A

– is a mathematical expression that shows
how the rate of reaction depends on the concentration
of the reactants.

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4
Q

Consider a simple hypothetical reaction involving only
one reactant.
A → products
The rate law for this reaction is expressed as:

A

rate = k[A]x
where:
k – rate constant
power of x – order of the reaction with respect
to reactant A

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5
Q

Zero-order reaction (x=0)

A

– has a constant rate
that is equal to its rate constant regardless of
changes in the concentration of the reactant.

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6
Q

Zero order reaction rate expressed as

A

rate = k[A]⁰ = k

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7
Q

First-order reaction (x=1)

A

general, the rate increases
in the same order as the concentration of the
reactant.

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8
Q

First order reaction aa

A

rate = k[A]¹ = k[A]

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9
Q

Second-order reaction (x=2)

A

increasing the
reactant concentration to twice as much as
quadruples the original reaction rate. A triple
increase in concentration means a ninefold
increase in reaction rate.

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10
Q

Second order reaction

A

rate = k[A]²

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