Chemical Kinematics Flashcards
Rate of a Reaction
– defined as the change in the
concentration of reactants or products per change in
time.
Rate=
Rate Law
– is a mathematical expression that shows
how the rate of reaction depends on the concentration
of the reactants.
Consider a simple hypothetical reaction involving only
one reactant.
A → products
The rate law for this reaction is expressed as:
rate = k[A]x
where:
k – rate constant
power of x – order of the reaction with respect
to reactant A
Zero-order reaction (x=0)
– has a constant rate
that is equal to its rate constant regardless of
changes in the concentration of the reactant.
Zero order reaction rate expressed as
rate = k[A]⁰ = k
First-order reaction (x=1)
general, the rate increases
in the same order as the concentration of the
reactant.
First order reaction aa
rate = k[A]¹ = k[A]
Second-order reaction (x=2)
increasing the
reactant concentration to twice as much as
quadruples the original reaction rate. A triple
increase in concentration means a ninefold
increase in reaction rate.
Second order reaction
rate = k[A]²