Chemical Equilibrium [Unit 3] Flashcards
Reversible Reaction
A reaction which proceeds in both the forward and reverse direction
- Indicated by ⇌
Forward Reaction
→ Forming products
Reverse Reaction
← Forming reactants
Equilibrium
The point in a reversible reaction where there is no change in the concentration of products and reactants
- Where the rate of the forward and reverse reactions are equal
Dynamic Equilibrium
Both the forward and reverse reactions are occurring
- No change overall
- Steady-state (Properties are constant)
- Only occurs in a closed system
Static Equilibrium
The forward and reverse reactions do not occur
- No change at all
Rate of Reaction
How fast a reaction takes place
Extent of a Reaction
How many of the reactants are turned into products in the time taken to reach equilibrium
Closed System
Does not allow matter to be transferred with the surroundings
- Energy can be transferred to and from the surroundings
- Has a lid
Open System
Matter and energy can be transferred to and from the surroundings
- Reactants or products may be lost to the environment
- Prevents equilibrium from being reached
Parts of a Chemical System
- Boundary - Barrier between chemical and surroundings (E.g. The glassware/beaker)
- System - Chemicals involved in the reaction
Links between Collision Theory and Equilibrium
- As reactants are used up, the forward reaction slows down
- As more product is formed, the reverse reaction speeds up
Eventually a point is reached where the rates are equal and equilibrium is reached
In Collision Theory Particles Must:
- Collide with at least a minimum amount of kinetic energy
- Collide with the correct orientation
Application of Collision Theory
- What happens to the reactants and products over time?
- How does that affect the number of collisions between reactants and products?
- Do more reactant or product particles now satisfy the conditions of collision theory?
- What happens to the rate of the forward and reverse reaction?
Application of Collision Theory in a Forward Reaction
- Reactants decrease over time - Less particles
- Fewer particles = Less collisions
- Less reactant particles meet the conditions of collision theory - Lower concentration = Less collisions
- Fewer successful collisions → Decrease in the rate of the forward reaction