chemical equilibrium Flashcards
when equilibrium lies to the right-
more products than reactants, -G forward
when equilibrium lies to the left-
more reactants than products, +G forwards
K<1
lies left
K>1
lies right
K (and Q) expression
K= products/ reactants
NO SOLIDS OR LIQUIDS
Manipulation of k expression
1) reversal
K=1/K
2) Multiplying
K=K^n
3) Dividing
K=K^r/n
what does RICE stand for
Reaction, initial, change, equilibrium
Right shift
reactants decrease, K>Q
left shift
Reactants increase, K<Q
equation for delta G
G=-RT ln K
(R=8.314 J/k*mol)
shift when increasing reactant molarity
right
shift when decreasing reactanr molarity
lefy
shift when increasing product molarity
left
shift when decreasing product molarity
right
+H
Endothermic, heat is a reactant