Chemical Characteristics of Water Flashcards

1
Q

What are the four main sources for inorganic and organic species?

A

1) Contact of water with minerals, rocks, and soils

2) Rain in contact with the atmosphere

3) Decomposition of organic matter in the environment

4) Municipal, industrial, agricultural and human activities

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2
Q

What are the main inorganic constituents?

A

Cations: calcium, magnesium, sodium, potassium (Ca2+, Mg2+, Na+, K+)

Anions: carbonate, bicarbonate, sulphate, chloride, nitrate (CO32-, HCO3-, SO42-, Cl-, NO3-)

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3
Q

What causes hardwater?

A

Calcium and Magnesium (Ca2+ and Mg2+)

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4
Q

What is the typical order for arranging cations and anions in the meq/L graphical representation of possible pairs?

A

Cations: Ca2+, Mg2+, Na+, K+, anything else

Anions: HCO3-, SO42-, Cl-, anything else

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5
Q

What is the point of the graphical representation of pairs?

A

To make sure the sum of meq/L of cations is equal to that of the anions

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6
Q

What happens to inorganic compounds in water?

A

They dissociate into ions

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7
Q

What are the 3 inorganic constituent indicators?

A

pH
Alkalinity
Hardness

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8
Q

What is alkalinity?

A

A measure of water’s capacity to neutralize acids (ability to absorb H+ without significant pH change)

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9
Q

What are the major contributors to alkalinity?

A

Bicarbonate, carbonate, and hydroxide

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10
Q

What are the typical units of alkalinity?

A

meq/L
mg/L as CaCO3

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11
Q

What is the typical pH value for phenolphthalein alkalinity?

A

8.3

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12
Q

A pH value below 8.3 usually means there is no carbonate present as it has been converted to bicarbonate, true or false?

A

True

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13
Q

A pH value below 4.5 usually means there is no bicarbonate present as it has been converted to carbonic acid, true or false?

A

True

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14
Q

Hardness is cause by what?

A

Multivalent Cations
(mainly calcium and magnesium in natural waters)

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15
Q

What would happen if you tried to wash dishes with hard water and soap?

A

The hard water would reduce the soaps cleaning action

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16
Q

What is the most common and troublesome form of hardness?

A

Calcium Bicarbonate (Ca(HCO3)2

It is picked up by rain water passing through limestone

17
Q

What is total hardness?

A

The combination of calcium and magnesium hardness

18
Q

What are the units of hardness?

A

mg/L of CaCO3

19
Q

What ions mainly contribute to temporary hardness?

A

Bicarbonate and Carbonate
(HCO3- and CO32-)

20
Q

What is carbonate hardness?

A

The combination of bicarbonate and carbonate hardness
(also known as temporary hardness)

21
Q

What ions mainly contribute to permanent hardness?

A

Chloride and Sulfate
(Cl- and SO42-)

22
Q

What is non-carbonate hardness?

A

The combination of chloride and sulfate hardness
(also known as permanent hardness)

23
Q

What is carbonate hardness typically equal to?

A

Alkalinity
(or the concentration of bicarbonate in mg/L as CaCO3)

24
Q

Give the range in mg/L as CaCO3 for the following degrees of hardness:
Soft
Moderately Hard
Hard
Very Hard

A

0-50
50-150
150-300
300+

25
Q

What is TOC?

A

Total Organic Carbon
(amount of organic matter)

26
Q

What are the 2 major sources of TOC in raw water?

A

Natural Organic Material (NOM)
Synthetic Organic Compounds (SOC)

27
Q

What are SOC’s?

A

1) Compounds formed through chemical reaction occurring during treatment (disinfectant byproduct or DBP like trihalomethanes)
2) Compounds originating from human activities

28
Q

Where do NOM’s originate from?

A

The degradation and end product of:
- plants and animal material
- microorganisms

29
Q

What are NOM’s?

A

Proteins
Carbohydrates
Lipids
Humic substances
Fluvic Substances

30
Q

What is a type of SOC formed in water treatment?

A

Disinfectant Byproduct (DBP)

31
Q

How are DBP’s formed?

A

The combination of disinfectants (chlorine) and natural organic material

32
Q

What are the two main groups of DBP’s?

A

THM’s and HAA’s
(Trihalomethanes and Haloacetic Acids)

Both of which are carcinogens