Chemical Characteristics of Water Flashcards
What are the four main sources for inorganic and organic species?
1) Contact of water with minerals, rocks, and soils
2) Rain in contact with the atmosphere
3) Decomposition of organic matter in the environment
4) Municipal, industrial, agricultural and human activities
What are the main inorganic constituents?
Cations: calcium, magnesium, sodium, potassium (Ca2+, Mg2+, Na+, K+)
Anions: carbonate, bicarbonate, sulphate, chloride, nitrate (CO32-, HCO3-, SO42-, Cl-, NO3-)
What causes hardwater?
Calcium and Magnesium (Ca2+ and Mg2+)
What is the typical order for arranging cations and anions in the meq/L graphical representation of possible pairs?
Cations: Ca2+, Mg2+, Na+, K+, anything else
Anions: HCO3-, SO42-, Cl-, anything else
What is the point of the graphical representation of pairs?
To make sure the sum of meq/L of cations is equal to that of the anions
What happens to inorganic compounds in water?
They dissociate into ions
What are the 3 inorganic constituent indicators?
pH
Alkalinity
Hardness
What is alkalinity?
A measure of water’s capacity to neutralize acids (ability to absorb H+ without significant pH change)
What are the major contributors to alkalinity?
Bicarbonate, carbonate, and hydroxide
What are the typical units of alkalinity?
meq/L
mg/L as CaCO3
What is the typical pH value for phenolphthalein alkalinity?
8.3
A pH value below 8.3 usually means there is no carbonate present as it has been converted to bicarbonate, true or false?
True
A pH value below 4.5 usually means there is no bicarbonate present as it has been converted to carbonic acid, true or false?
True
Hardness is cause by what?
Multivalent Cations
(mainly calcium and magnesium in natural waters)
What would happen if you tried to wash dishes with hard water and soap?
The hard water would reduce the soaps cleaning action