Chemical Changes and Structure: Bonding Flashcards

1
Q

When are ionic compounds formed?

A

When two atoms bond where there is a large difference in electronegativity.

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2
Q

How can ionic compounds be identified?

A

By their properties which include high melting points, conductors of electricity when molten and soluble in polar solvents

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3
Q

Covalent compounds are classed as what?

A

Polar or non-polar

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4
Q

Polar covalent bonds are formed when?

A

Two atoms with different electronegativity values form a covalent bond. The atom with the higher electronegativity value is assigned the symbol δ- and the atom with the lower value is assigned the symbol δ+

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5
Q

The bonding continuum is used to describe what?

A

The variation in bonding from ionic at one end to covalent at the other end. Polar covalent is in the middle of the continuum.

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6
Q

The attraction between covalent molecules are known as what?

A

Van der Waals’ forces

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7
Q

What are the three types of van der Waals’ forces, name them in order from weakest to strongest?

A

London dispersion forces (LDF), permanent dipole-permanent dipole interactions (pdp-pdp) and hydrogen bonds

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8
Q

Non-polar covalent bonds are formed between what?

A

Two atoms with the same electronegativity value. The atoms have an equal attraction for electrons in the covalent bond.

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9
Q

Compounds with polar bonds will form what?

A

Polar molecules provided the molecule is not symmetrical

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10
Q

Compounds with non-polar bonds will form what?

A

Non-polar molecules

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11
Q

Symmetrical compounds with polar bonds (such as CO2) will form what?

A

Non-polar molecules

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12
Q

Non-polar molecules are attracted to what?

A

Other non-polar molecules by LDF

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13
Q

Polar molecules are attracted to what?

A

Other polar molecules by pdp-pdp interactions or hydrogen bonding

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14
Q

Permanent dipole-permanent dipole interactions occur between what?

A

Molecules where the molecule has a permanent dipole, for example, between ICl molecules

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15
Q

Hydrogen bonding occurs where?

A

Between molecules that contain an atom of H bonded to an atom of N, O or F, for example, between alcohol molecules

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16
Q

Molecules with stronger intermolecular forces will have what?

A

Higher melting and boiling points and a higher viscosity

17
Q

Solubility can be predicted using what?

A

The ‘like dissolves like’ rule. In other words, polar molecules and ionic substances will dissolve in polar solvents; non-polar compounds will dissolve in non-polar solvents.