chemical bonding (8.0-8.4) Flashcards
what is ionic bonding?
attraction between oppositely charged ions
what is covalent bonding?
sharing of electrons
what is metallic bonding?
free electrons hold metal ions together
what is an octet?
eight electrons main group elements s^2p^6
what is a lewis structure?
- counts electrons in the outer valance shell (s & p)
- draw one lewis dot for each valence electron around an atom
- draw up to four unpaired electrons, then pair additional electrons
exceptions to lewis structure (transition metals)
- do. not necessarily follow the octet rule
- lose the valence s&p electrons, first then lose the d electrons necessarily for the given ion charge
exceptions to lewis structure (main group metal)
lose electrons to reach lower noble gas congifuration
exceptions to lewis structure (nonmetals)
gain electrons to reach higher noble gas configuration “octet”
exception to lewis structure (hydrogen metals)
needs two electrons to reach 1s^2 closed shell for H- (duet)
what is the equation for coulomb energy?
E=KQ1Q2/d
what are properties of ionic substances?
- negative & positive ions arranged in a lattice
- held together by electrostatic attraction of opposite charges
what is lattice energy?
the energy required to separate a solid ionic compound into its gaseous ions (endothermic)
what are lattice energy trends?
- increases with a charge on the ions, and with smaller ionic sizes
- decreasing the size of the ion
- larger for ions with higher charges
what is a covalent bond?
are atoms that share electrons. for covalent bonds to form the attractions must be greater than the repulsions
- molecular compounds are held together by covalent bonds
what are electrostatic interactions in covalent bonds?
- attractions between electrons and nuclei
- repulsions between electrons and nuceli
what is the number of bonds for nonmetals?
- the group number is the number of valence electrons
- to get an octet, like the nearest noble gas, in the simple covalent molecules for nonmetals, the number of bonds needed will be the same as the electrons needed to complete the octect
what are lone pairs?
electron located on only one atom in a lewis structure
what are bonding pairs?
two shared electrons in a lewis structure, represented by a line
what are single bonds?
some atoms share only one pair of electrons
what are double bonds?
two pairs need to be shared to reach & octect
what are triple bonds?
three pairs are shared between the atoms
what is bond polarity?
is the measure of how equally or unequally the electrons in a covalent bonds are shared
what are nonpolar covalent bonds?
the electrons are shared equally. F2 (any diatomic element)
what are polar covalent bonds?
one of the atoms attracts electrons to itself with a greater force HF or LiF
what is electronegativity?
is the ability of an atom in a molecule to attract electron to itself
- increases from left to right (except to noble gas) from top to bottom
what are polar covalent bonds?
when two atoms share electrons unequally. electrons tend to speed more around the more electronegative
what is a dipole?
when two equal, but opposite charges are separated by distances a dipole forms