chemical bonding (8.0-8.4) Flashcards
what is ionic bonding?
attraction between oppositely charged ions
what is covalent bonding?
sharing of electrons
what is metallic bonding?
free electrons hold metal ions together
what is an octet?
eight electrons main group elements s^2p^6
what is a lewis structure?
- counts electrons in the outer valance shell (s & p)
- draw one lewis dot for each valence electron around an atom
- draw up to four unpaired electrons, then pair additional electrons
exceptions to lewis structure (transition metals)
- do. not necessarily follow the octet rule
- lose the valence s&p electrons, first then lose the d electrons necessarily for the given ion charge
exceptions to lewis structure (main group metal)
lose electrons to reach lower noble gas congifuration
exceptions to lewis structure (nonmetals)
gain electrons to reach higher noble gas configuration “octet”
exception to lewis structure (hydrogen metals)
needs two electrons to reach 1s^2 closed shell for H- (duet)
what is the equation for coulomb energy?
E=KQ1Q2/d
what are properties of ionic substances?
- negative & positive ions arranged in a lattice
- held together by electrostatic attraction of opposite charges
what is lattice energy?
the energy required to separate a solid ionic compound into its gaseous ions (endothermic)
what are lattice energy trends?
- increases with a charge on the ions, and with smaller ionic sizes
- decreasing the size of the ion
- larger for ions with higher charges
what is a covalent bond?
are atoms that share electrons. for covalent bonds to form the attractions must be greater than the repulsions
- molecular compounds are held together by covalent bonds
what are electrostatic interactions in covalent bonds?
- attractions between electrons and nuclei
- repulsions between electrons and nuceli