Chemical Bonding Flashcards
1
Q
Metallic
A
- Electrostatic attraction between metal cations and sea of delocalised valence electrons
- Sea of delocalised electrons easily maintains a flow of charge through the lattice
- Non-directional bonding allows cations to form interactions with valence e allowing to be malleable
- conductive as they have both mobilised and charged particles
- (lustrous) Light rays are reflected off the delocalised sea of electrons
- Strong metallic bonds holds layers of tightly packed cations in fixed positions
- high melting and boiling points
2
Q
Ionic
A
- Electrostatic attraction between alternating metal cations & non-metal anions
- Consists of rigid 3D crystalline lattice of alternating metal cations & non-metal anions
- Cannot conduct electricity in solid form as all charged particles within the substance are held in a fixed position and are unable to transfer charge through the compound
- Can conduct electricity in molten state as the bonds are broken and the ions are now mobile and capable of carrying electrical current throughout the substance
- Strong ionic bonds which means they have high melting & boiling points
- Not malleable or ductile as when force is applied, like charges align making it repel and shatter
3
Q
Covalent Molecular
A
- bonds between 2 or more non-metal atoms
- covalent substance atoms will tend to share their valence electrons rather than gain or lose them completely
- intramolecular forces hold the atoms within the molecules, this force is very strong and requires a lot of energy to break
- intermolecular forces in between molecules and are very weak
- low melting and boiling points
- Consist of neutral molecules and as such, do not have free electrons. Since there are no freely mobile charged particles, they don’t conduct electricity
- The weak intermolecular forces mean that the atoms are easily pushed past each other
4
Q
Covalent Network
A
- bonding of two or more non-metal atoms
- Giant 3D lattice
- Between each atom are extremely strong covalent bonds that require high levels of energy to break
- have very high melting and boiling points as there is no intermolecular forces and only intramolecular forces which are very strong
- No free electrons or mobile charged particles to carry the charge through the network lattice (except graphite)
- The strong covalent bonds between each atom, together with the large number of these bonds in the lattice, make covalent network substances extremely hard (except graphite)
- If the lattice shears it will disturb the three-dimensional matrix and shatter
- most cases covalent networks won’t be conductors of electricity as each atom is held in a fixed position by covalent bonds and valence electrons are shared between atoms