Chemical Bonding Flashcards
Factors affecting bond strength/energy
Directly proportional to multiplicity
Inversely proportional to size
Exceptions
Second period
C-C>N-N>O-O>F-F
Halogens
Cl2>Br2>F2>I2
Bond angle depends on
Inversely proportional to LP on central atom
Directly proportional to EN and size of surrounding atom
Bond angle depends on
Inversely proportional to LP on central atom
Directly proportional to EN and size of surrounding atom
Overlapping is directly proportional to
Closeness to nucleus
1s1s>2s2s>3s3s
1s1s>1s2s>2s3s
directional nature
2s2s>2s2s>2s2p
1s1s>2s2p>2s2s
Formal charge
FC = valance e_ - ( no of bonds + electrons required for octet )
Dipole moment (u)
SI unit. Cm
CGS. esucm
Debye
1debye = 1×10^-18 esu cm
= 3.34×10^-30 Cm
More the EN more is u
HF>HCl>HBr>HI
q.d
CCl>CF>CBr>CI