Chemical Analysis Flashcards

1
Q

Pure substance in chemistry

A

Something that contains only 1 compound/element throughout, not mixed with anything else

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2
Q

Pure substance in everyday language

A

Substance that hasn’t had anything added to it so is in natural unadulterated state, like pure milk

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3
Q

How to test purity of sample

A
  • measure melting/boiling point
  • compare with that of pure substance - data book
  • closer your sample is to pure value, purer it is
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4
Q

Effect of impurities on melting point + range

A
  • lower melting point
  • increase melting range
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5
Q

Effect of impurities on boiling point + range

A
  • increases boiling point
  • sample may boil at range of temps
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6
Q

Formulations

A

Mixtures with exact amounts of components for a precise purpose

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7
Q

How to make formulations

A
  • follow a formula
  • add each component in precisely measured formula
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8
Q

Why do formulations have precise measurements

A

Quantity of each component contributes to properties so formulation meets required function

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9
Q

Example of formulations in pharmaceutical industry

A
  • formulation of pills can be altered so that:
    -drug delivered to correct part of body
    -delivered at right concentration
    -its consumable
    -has long enough shelf life
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10
Q

Examples of formulations in everyday life

A
  • fuels
  • cleaning agents
  • paints
  • medicines
  • alloys
  • fertilisers
  • foods
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11
Q

Purpose of chromotography

A
  • separate substances in mixture
  • can then identify substances
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12
Q

Phases of chromotography

A
  • mobile
  • stationary
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13
Q

Mobile phase

A
  • molecules can move
  • always liquid or gas
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14
Q

Stationary phase

A
  • molecules can’t move
  • can be solid or really thick liquid
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15
Q

What is the mobile phase in paper chromotography

A

The solvent

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16
Q

What is the stationary phase in paper chromotography

17
Q

What happens when chemicals are in mobile phase in paper chromotography

A
  • dissolve in solvent
  • move a little bit
18
Q

What happens when chemicals are in stationary phase in paper chromotography

A
  • bind to paper
  • don’t move
19
Q

When do chemicals switch phases in paper chromotography

A

Continuously

20
Q

What determines how much chemicals move up paper in chromotography

A

How much time they spend in each phase

21
Q

How can you tell solubility of chemicals in paper chromotography

A
  • the more soluble a chemical is, the more time it spend in the mobile phase
  • the more time it spends in the mobile phase, the further up the paper it will go
22
Q

Why do more soluble chemicals move further up page in chromotography

A

Molecules are less attracted to paper so spend more time in mobile phase

23
Q

How to know a substance in pure from chromotography

A

It will only form 1 spot in any solvent

24
Q

How to know substance is impure from chromotography

A

It will form multiple spots

25
Chromatogram
Result of chromotography analysis
26
What does Rբ value mean in chromotography
- ratio between distance travelled by solute and solvent - larger value means substance travelled further
27
How can Rբ value be used to identify compounds
Different compounds have different Rբ values in different solvents
28
Test for hydrogen
- hold burning splint at open end of test tube of gas - positive - hydrogen burns rapidly with **squeaky pop** sounds
29
Test for oxygen
- glowing splint inserted into test tube of gas - positive - splint **relights** in oxygen
30
Test for carbon dioxide
- shake / bubble gas through aqueous solution of calcium hydroxide (limewater) - positive - solution turns **cloudy**
31
Test for chlorine
- put damp litmus paper into gas - positive - litmus paper bleached, turns **white**