chemical analysis Flashcards

1
Q

in chemistry, what is a pure substance

A

a substance made up of a single element or compound, not mixed with any other substances

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2
Q

in everyday language, what is a pure substance

A

a substance that has nothing added to it, in its natural state

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3
Q

boiling & melting points for pure substances are…

A

at a fixed temperature, eg pure water would only be boiled at 100’C

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4
Q

boiling & melting points for impure substances are…

A

over a range, eg salty water would boil from 100-105’C

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5
Q

formulation

A

mixture that has been designed as a useful product

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6
Q

how are formulations made

A

by mixing components in carefully measured quantities to get the required properties

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7
Q

formulation examples

A
  • fuel
  • cleaning agent
  • paint
  • medicine
  • alloys
  • fertilisers
  • food
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8
Q

method to separate dyes

A

chromatography

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9
Q

phases of chromatography

A

stationary & mobile phase

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10
Q

what is the stationary phase

A

the chromatography paper

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11
Q

what is the mobile phase

A

the solvent (usually water)

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12
Q

what must you use to draw the line for chromatography and why

A

pencil
this is insoluble in the solvent so it will not run

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13
Q

where must the water be in relation to the pencil line

A

water line must be below the pencil line to stop inks mixing with the solvent

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14
Q

what does the distance the dots move tell you

A

how soluble the ink is in the solvent - if it moves to the top it is very soluble

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15
Q

if the dot doesnt move off the pencil line what does that tell you?

A

the ink is insoluble in the solvent

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16
Q

explain how the inks are separated using paper chromatography

A

inks have different solubilities. this means they move up the paper at different speeds/distances

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17
Q

what is Rf value

A

the ratio of the distance moved by a compound to the distance moved by the solvent

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18
Q

how can you express Rf

A

Rf = distance dot travelled / distance solvent travelled

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19
Q

how do we use Rf values?

A

theyre used to identify substances. each substance has a specific Rf value so we use these to confirm what is in a mixture

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20
Q

what value is Rf alway below

A

1

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21
Q

how many spots would you get for a pure substance

A

one

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22
Q

how many spots would you get for a mixture

A

more than one

23
Q

test for hydrogen

A

burning splint
makes a squeaky pop noise

24
Q

test for oxygen

A

glowing splint
splint relights

25
Q

test for carbon dioxide

A

bubble through limewater
limewater turns milky/cloudy

26
Q

test for chlorine

A

damp blue litmus paper
turns bleached white

27
Q

test for ions which produces colour when burnt

A

flame tests

28
Q

what can you test with a flame test

A
  • lithium
  • sodium
  • potasium
  • calcium
  • copper
29
Q

flame test - lithium

A

crimson red

30
Q

flame test - sodium

A

yellow

31
Q

flame test - potassium

A

lilac

32
Q

flame test - calcium

A

orange-red

33
Q

flame test - copper

A

green

34
Q

what should you do if identifying ions in a tablet

A

crush into a powder or dissolve in water

35
Q

what happens if there is a mixture of ions in a sample

A

some flame colours can be masked

36
Q

hydroxide to identify some metal ions in a solution

A

sodium hydroxide

37
Q

what can you test with sodium hydroxide

A
  • aluminium
  • magnesium
  • calcium
  • iron (II)
  • iron (III)
  • copper (II)
38
Q

s.h - aluminium, calcium, magnesium

A

white precipitate

39
Q

s.h - copper (II)

A

blue precipitate

40
Q

s.h - iron (II)

A

green precipitate

41
Q

s.h - iron (III)

A

brown precipitate

42
Q

how can you distinguish between aluminium magnesium and calcium

A

add excess sodium hydroxide
aluminium hydroxide precipitate will dissolve

43
Q

half equation to show formulation of the blue precipitate between copper (II) and sodium hydroxide

A

Cu2+ 2OH –> Cu(OH)2

44
Q

test for carbonate

A

react with a dilute acid
forms carbon dioxide gas
identified using limewater, goes cloudy

45
Q

test for halide

A

silver nitrate solution
presence of dilute nitric acid
precipitates form

46
Q

chloride & silver nitrate

A

white precipitate

47
Q

bromide & silver nitrate

A

cream precipitate

48
Q

iodide & silver nitrate

A

yellow precipitate

49
Q

test for sulphate

A

barium chloride in presence of dilute hydrochloric acid

50
Q

sulphate & barium chloride

A

white precipitate

51
Q

advantages of instrumental methods

A
  • accurate
  • more sensitive
  • rapid
  • ease of use
  • reliable / efficient
  • sample doesnt get used up
52
Q

instrumental method to detect metal ions in solution

A

flame emission spectroscopy

53
Q

how is flame emission spectroscopy carried out

A

sample is put in a flame
light given out is passed through a spectroscope
the output is a line spectrum