Chem Lab Vocab. Kinetics Flashcards
transition state or activated complex
an arrangement of two reactant molecules which can either go on to form products or fall apart again into the unchanged reactants
steric factor
an empirical factor which takes into account the fact that molecules must collide in a certain orientation in order to react
0th order reaction
a reaction in which the reaction rate is independent of reactant concetration
activation energy
the energy barrier which must be overcome in order for a reaction to occur
initiation
the first step in a chain reaction, where chain carriers are formed from a reactant
steady state approximation
the assumption that the rate of change of a reaction intermediate is equal to zer0
0th order reaction
a reaction for which a graph of concentration vs. time yields a straight line