chem-9 Flashcards

1
Q

Where did the atmosphere come from?

A

One theory suggests that the early atmosphere came from intense volcanic activity, which released gases that made the early atmosphere very similar to the atmospheres of Mars and Venus today. These atmospheres have:

a large amount of carbon dioxide
little or no oxygen
small amounts of other gases, such as ammonia and methane
Volcanic activity also released water vapour, which condensed as the Earth cooled to form the oceans. Nitrogen was probably also released by volcanoes which gradually built up in the atmosphere because it is unreactive.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

what is the modern atmosphere like?

A

For approximately 200 million years, the proportions of different gases in the atmosphere have been relatively stable.
-nitrogen 80% approx
-oxygen 20% approx
-carbon dioxide, water vapour and noble gases

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

How has oxygen increased

A

Plants make their own food by photosynthesis. In this process, carbon dioxide is reacted with water to produce glucose, with oxygen as a by-product:

carbon dioxide + water → glucose + oxygen

6CO2(g) + 6H2O(l) → C6H12O6(aq) + 6O2(g)

Scientists think that algae first evolved approximately 2.7 billion years ago, and soon after this oxygen began to exist in the atmosphere. Photosynthesis by primitive plants and algae released oxygen, which gradually built up in the atmosphere. Eventually, the amount of oxygen present in the atmosphere enabled animals to evolve.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Explain how carbon dioxide has decreased (sedimentary rocks)

A

Carbon dioxide is a very soluble gas. It dissolves readily in water. As the oceans formed, carbon dioxide dissolved to form soluble carbonate compounds so its amount in the atmosphere decreased. Carbonate compounds were then precipitated as sedimentary rocks, eg limestone.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

Explain how carbon dioxide has decreased (uptake by living organisms and creation of fossil fuels)

A

Carbon dioxide was also absorbed from the oceans into photosynthetic algae and plants. Many of these organisms, and the simple organisms in the food chains that they supported were turned into fossil fuels, eg crude oil, coal and natural gas, which all contain carbon.

Coal is a fossil fuel which was formed from trees which were in dense forests in low-lying wetland areas. Flooding caused the wood from these forests to be buried in a way that prevented oxidation taking place. Compression and heating over millions of years turned the wood into coal.

Crude oil and natural gas were formed from simple plants and tiny animals which were living in oceans and lakes. These small organisms died and their remains sank to the bottom where they were buried under sediments. The lack of oxygen prevented oxidation from occurring.

Over millions of years, heat and pressure turned the remains of the organisms into crude oil and natural gas. Natural gas contains the smallest molecules and is often found on top of crude oil, trapped under sedimentary rock.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Describe two reasons why the amount of carbon dioxide in the atmosphere decreased over time. (simple form)

A

Carbon dioxide dissolved in the oceans, and primitive plants used it for photosynthesis.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

What is the greenhouse effect

A

Without greenhouse gases in its atmosphere, the Earth would be about 18°C colder on average than it is now. That would make it too cold to support life as we know it.

Greenhouse gases present in the atmosphere include:

water vapour
carbon dioxide
methane
These greenhouse gases:

Absorb heat radiated from the Earth
then release energy in all directions, which keeps the Earth warm

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

How does the greenhouse effect work

A

electromagnetic radiation at most wavelengths passes through the Earth’s atmosphere
the Earth absorbs most of the radiation and warms up
the Earth radiates energy as infrared radiation
some of the infrared radiation goes into space
some of the infrared radiation is absorbed by greenhouse gases in the atmosphere
the lower atmosphere warms up

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

How are humans increasing the amount of greenhouse gases

A

farming cattle releases methane
farming rice in paddy fields releases methane
burning fossil fuels in vehicles and power stations releases carbon dioxide
deforestation releases carbon dioxide and reduces the absorption of carbon dioxide through photosynthesis

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

Are humans causing global warming?

A

Not everyone in the world agrees that humans are causing global warming by causing the release of greenhouse gases into the atmosphere. Some people believe that the current and ongoing rise in global temperatures is being caused by natural factors and cycles of climate change.

However, the vast majority of scientists do believe that humans are responsible for the increase in greenhouse gases and therefore global warming. This is because the majority of evidence in peer-reviewedjournals supports the theory that human activities are causing an increase in greenhouse gases and this is causing global warming.

However, climate science is complicated and it is difficult to predict and explain what will happen to global temperatures in the future, so scientists cannot be certain about global warming.

The media (eg websites, TV news, newspapers) may sometimes present opinions and articles which are simplified, inaccurate, based on only some of the evidence or biased. It is important for new evidence to be shared with as many people as possible, so that other scientists can check the results and interpretation, and repeat the experiments for themselves.

When evaluating the quality of evidence on an issue like global warming, you should consider:

who did the research and whether they are trustworthy, skilled and experienced
who funded the research, because that might cause some bias
what methods were used to collect and analyse the data, because that might cause uncertainties in the evidence base
which organisation is reporting or publishing the evidence

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

How is climate different from weather

A

Climate is different from weather because climate refers to the average temperature and cycles of weather over long periods of time - decades at least. You might talk about the weather being windy last week, or hotter last year than the year before. But unless you compare data for many years you cannot make a judgment about whether the climate is changing.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

What has the earth temp been like since it was formed

A

The Earth’s climate has been constantly changing since the Earth was formed 4.6 billion years ago. This includes several ice ages and periods of much warmer global temperatures. Until 200 years ago, these changes were all caused by natural changes such as volcanic eruptions and changes in the energy that reaches the Earth from the Sun.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

What is global warming

A

Global warming is not the same as climate change. Global warming is usually used to describe the warming of the climate in the past 200 years, which the vast majority of scientists are almost certain has been caused by human activities.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

What is one piece of evidence humans have caused global warming

A

One of the commonly used pieces of evidence that humans are causing global warming is that there is a strong correlation between the increase in global carbon dioxide levels caused by human activities and the increase in global temperatures over the same timescale.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

What are the effects of global warming

A

The effects of global warming include:

glaciers and polar ice melting
sea levels rising
patterns of rainfall changing, producing floods or droughts
habitats changing

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

Explain carbon footprint produced by a product and give an example

A

The carbon footprint of a product is the total amount of carbon dioxide (and other greenhouse gases) which are emitted over the full life cycle of a product, service or event.

For example, the carbon footprint of a car would include the carbon dioxide emitted by:

machinery whilst the metal is extracted from the Earth’s crust and processed
power stations which generate the electricity used to manufacture the car
the car itself when it is driven for many years
the machinery which is used to dispose of or recycle the car

16
Q

explain the carbon footprint of a person and an example

A

The carbon footprint of a person during one year would consist of the total amount of carbon dioxide released into the atmosphere by all of the activities they take part in, and the manufacture, use and disposal of all the products and resources they use. For example, a typical young person might:

use electricity at home, probably generated from fossil fuels, for lighting their room and using electronic devices
use a gas-powered boiler at home (which produces carbon dioxide) for heating and hot water
travel to school by bus or car (which probably runs on petrol or diesel)
eat beef or rice which have been farmed using methods that release methane
travel abroad once per year on an aeroplane (which produces carbon dioxide)

17
Q

combustion of hydrocarbons fuels

A

Most fuels contain carbon and/or hydrogen. When hydrogen atoms are present in a fuel, they are oxidised to water. Water is not a pollutant.

When there are lots of oxygen atoms present during combustion, the carbon atoms are completely oxidised to carbon dioxide. When there are fewer oxygen atoms present, carbon monoxide or carbon may be produced during combustion.

18
Q

complete combustion of hydrocarbons fuels

A

Complete combustion of a hydrocarbon fuel occurs when there is a good supply of oxygen. It releases the maximum amount of energy and produces carbon dioxide and water.

To construct a symbol equation for the complete combustion of a hydrocarbon fuel, remember that the fuel reacts with O2 and the only products are CO2 and H2O. For example, using methane (CH4) as the fuel:

methane + oxygen → carbon dioxide + water

CH4 + O2 → CO2 + H2O

When this equation is balanced, you get:

CH4 + 2O2 → CO2 + 2H2O

19
Q

incomplete combustion for hydrocarbon fuels

A

Incomplete combustion of a hydrocarbon fuel occurs when there is a poor supply of oxygen. Less energy is released. Water is still produced from the hydrogen atoms. Instead of carbon dioxide, you might get carbon monoxide or particulate carbon, known commonly as soot, or a mixture of both.

To construct a symbol equation for the incomplete combustion of a fuel, you need to read the question to see whether carbon monoxide (CO) or carbon (C) is produced. For example, using ethane (C2H6) as a fuel, and producing CO as one of the products:

ethane + oxygen → carbon monoxide + water

C2H6 + O2 → CO + H2O

When this equation is balanced, you get:

2C2H6 + 5O2 → 4CO + 6H2O

20
Q

What’s the problems with incomplete combustion

A

Carbon monoxide is a poisonous gas which binds to haemoglobin in your red blood cells, preventing them from carrying oxygen to the cells in your body. Carbon monoxide is colourless and has no smell, so it is very difficult to tell if you are breathing it in. It can be detected by electronic detectors which are often fitted near to boilers.

Particulate carbon can cause health problems for humans because it irritates the lining of the lungs, can make asthma worse, and perhaps even cause cancer. Particulate carbon can also cause global dimming, which may reduce rainfall.

21
Q

State some pollutants and their sources

A

Carbon dioxide, CO2- Complete combustion of any fuel containing carbon atoms
Carbon monoxide, CO- Incomplete combustion of any fuel containing carbon atoms
Particulate carbon, C (soot)- Incomplete combustion of any fuel containing carbon atoms
Unburned hydrocarbons- Hydrocarbon fuel molecules which have not been oxidised at all
Sulfur dioxide, SO2- Combustion of a fossil fuel which contains sulfur impurities
Nitrogen oxides, NOx- Oxidation of atmospheric nitrogen inside the engine of a car, lorry, etc

22
Q

How is sulfur dioxide form and what does it cause

A

Sulfur dioxide is caused when sulfur atoms which are present in some fossil fuels are oxidised:

sulfur + oxygen → sulfur dioxide

S + O2 → SO2

Sulfur dioxide is then further oxidised in the atmosphere to sulfur trioxide, SO3. This gas dissolves in rainwater to make acid rain, which is a dilute solution of sulfuric acid, H2SO4.

The two reactions are:

sulfur dioxide + oxygen → sulfur trioxide

2SO2 + O2 → 2SO3

And then:

sulfur trioxide + water → sulfuric acid

SO3 + H2O → H2SO4

Acid rain harms and kills plants and animals, especially those that live in aquatic environments. It can also damage man-made objects like statues and buildings.

23
Q

explain how nitrogen is formed and what it can cause

A

Nitrogen is not present in fuels, but the high temperatures and pressures inside a car engine can cause the nitrogen and oxygen in the air to react together to make oxides of nitrogen.

There are several compounds formed when nitrogen bonds with oxygen, but the two which are made inside engines are NO and NO2. These two pollutants are grouped together with the general formula NOx.

NOx gases can cause acid rain, and they also react in the atmosphere with other pollutants to make photochemical smog. Smog can have major health effects, causing asthma attacks and even death.