chem 22 jan Flashcards

1
Q

When would you use chromatography?

A

When separating two substances which are soluble in the same solvent

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1
Q

What would you call a solution where you cannot dissolve any more solute?

What about one in which you can?

A

Saturated and Unsaturated

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2
Q

What is the difference between a mixture and a compound?

A
  • A mixture is made up of substances which are not joined by chemical bonds, whereas in a compound they are joined together.
  • In a mixture, the components do not take on new properties, whereas they do take on new properties in a compound.
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3
Q

Define filtration

A

A process used to separate a solid, insoluble solute from a solvent

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4
Q

Give two ways in which you can increase the solubility of a substance?

A

increasing the temperature- (as this would provide energy to the solute particles, allowing them to move and create space. this would allow more solvent to disperse throughout the solution)

and stirring the solution

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5
Q

Which type of separating technique would you use to separate sea water but keep the water?

A

distillation

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6
Q

What is the advantage of distillation over evaporation for separating a mixture?

A

In distillation the solvent is kept, whereas in evaporation this will be lost as a gas

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7
Q

Why are mixtures easy to separate?

A

Because the substances in the mixture are not chemically joined

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8
Q

what happens when a substance dissolves?

A

The solvent particles surround the solute particles.

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9
Q

what are mixtures

A

mixtures consist of substances that are not chemically joined together. These substances can be both compounds and elements.

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10
Q

what are the two types of mixtures and what are their properties?

A

heterogeneous mixtures- separate substances are visible.

homogeneous mixtures- unable to distinguish between different substances.

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11
Q

what is a pure substance

A

A pure substance contains only one substance- it is not mixed with anything else. All its particles are of the same type.

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12
Q

How can you identify pure substances?

A

-If you heat up both pure and impure substances uThe melting/boiling points of pure substances are one exact temperature. However, in impure substances, the melting/boiling points are within a range of temps

This is bc there are substances which each have different melting/boiling points.

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13
Q

solute

A

The substance that is dissolved in the solvent

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14
Q

solvent

A

the substance (usually liquid) which the solute is dissolved in.

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15
Q

solution

A

The resulting mixture of the solvent and solute.

16
Q

insoluble

A

if a solute cannot dissolve in the solvent, it is insoluble.

17
Q

soluble

A

if a solute can dissolve in the solvent, it is soluble

18
Q

saturated

A

when the solvent is so concentrated to the point where no more solute can be dissolved in it.

19
Q

concentrated

A

A concentrated solution is one that has a relatively large amount of dissolved solute in a given volume of solvent.

20
Q

why do solutions become saturated

A

due to how packed the particles have become, there is no space for more particles to be allowed in.

21
Q

how does temperature affect solubility?

A

When a solvent is at a high temperature, the particles in it obtain more energy allowing them to disperse and move further apart which increases solubility.

22
Q

immiscible

A

when two substances cant form a homogeneous mixture

23
Q

apparatus for filtration

A

conical flask, filter funnel, filter paper.

note that filtrate is the liquid left after solute is filtered out and residue is the solute that is left in the filter paper.

24
Q

what is evaporation used for

A

to separate soluble solid from a solution. You will be left with the soluble solid.

25
Q

apparatus for evaporation

A

evaporating basin, tripod, heat proof mat, bunsen burner

26
Q

what is distillation used for?

A

the method of distillation is used to separate solvent from solute, while maintaining both substances.

27
Q

what is the method of distillation

A

-assemble apparatus
-pour the mixture into the round bottom flask. Ensure it is not more than half full
-heat the mixture in the flask. As it comes to a boil, water vapour will escape and pass through the neck of the flask and into the condenser where it will condense.
- the water (liquid) will be collected in the flask.

28
Q

when is fractional distillation used?

A

It is used when the mixture that is to be separated consists of two liquids. The process depends on the two different boiling points of the liquids.

29
Q

distillation apparatus

A

-round bottom flask, bunsen burner, distillation column (fractional), condenser, receiver flask, clamp

30
Q

fractional distillation method

A

-Arrange the fractional distillation apparatus. This includes a distillation flask, a fractionating column on top of it, a condenser, a thermometer, and a collection flask.

-pour the mixture into a round bottom flask

-attach the fractionating column.

-Heat the flask with the temperature of the lowest boiling point among the liquids in the mixture.

-as the mixture comes to a boil, the liquid with that boiling point will evaporate and condense first.

-The thermometer will measure the heat so that we know which liquid has evaporated.

-Increase the temp according to the boiling point of the next liquid. The liquid left will then evaporate and condense. It will then collect in another reciever flask.

31
Q

what is retention factor?

A

retention factor (rf) is:
the distance travelled by dye or other solute/ distance travelled by solvent.

note that rf is always less than one bc it is always a smaller number divided by a larger number

this is used to obtain a certain number e.g 0.5 which tells us what the unknown substance is.

32
Q

explain why in chromatography some substances travel further up the paper than others

A

due to different solubility. A solvent that dissolves a particular substance well will carry that substance further.