Chem 2 exam outline Flashcards
Factors Affecting the Rate of a Reaction. (Changes in Temperature and Concentration)
An increase in temperature increases the rate of reaction, as temp increases a greater fraction of molecules have enough thermal energy to surmount the activation barrier
Concentration= reactant concentration decreases with time, product concentration increases with time
n=0 is zero order, rate is independent of the concentration of A
n=1 is first order, rate is directily proportional to the concentration of A
n=2 second order, rate is proportional to the square of the concentration of A
Effect of Changes in Pressure on Gas Solubility
If the pressure increases, the solubility of the ionic compound not affected
if pressure increases solubility of gases increases
Effect of Temperature on the Solubility of Ionic Compounds
If temp increases solubility of ionic compound increases
if temp increase solubility of gases decrease
Determine whether a solution is unsaturated, saturated, or supersaturated using the Solubility vs. Temperature graph
unsaturated= solution containing less than the equilibrium amount of solute, if you add additional solute it will dissolve
saturated= solution that dissolved solute is in the dynamic equilibrium with the solid solute, if you add additional solute it will not dissolve
supersaturated= containing more than the equilibrium amount of solute,
See solubility and temp graph figure 14.11 page 591
Write the reaction rate expressions for a reaction
rate of reaction= change in amount of reactants divided by change in time
rate expression example: H2 + I2 —> 2 HI
Rate expression see notes chapter 15, 2/7 practice problems