Chem 1b Flashcards

1
Q

Dynamic equlibrium

A

The concentrations of all substances are constant and the rate of the forward reaction equals the rate of the reverse reaction.

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2
Q

Le Chateliers Principle

A

If a change is made to a reaction at eqm. then the position of equilibrium will change so as to oppose that change if possible.

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3
Q

Enthalpy change

A

The amount of heat energy taken in or given out during any change in a system at constant pressure.

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4
Q

Standard enthalpy change

A

The enthalpy change for a reaction at 298 K and 100 kPa with all reactants and products in their standard states.

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5
Q

Specific heat capacity

A

The heat required to raise the temperature of 1 gram of a substance by 1 Kelvin. It is measured in J g–1 K–1.

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6
Q

Standard enthalpy of combustion

A

Enthalpy change which occurs when 1 mole of a substance is completely burnt in oxygen at 298K and 100kPa.

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7
Q

Standard enthalpy of formation

A

Enthalpy change which occurs when 1 mole of a substance is formed from its elements at 298K and 100kPa.

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8
Q

Bond dissociation enthalpy

A

Enthalpy change when 1 mole of a specific bond in a specific gaseous molecule is broken at 298 K and 100 kPa.

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9
Q

Mean bond enthalpy

A

The average amount of energy needed to break a covalent bond averaged over a range of gaseous compounds at 298 K and 100 kPa.

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10
Q

Enthalpy change of solution

A

Enthalpy change when 1 mole of an ionic substance dissolves in water to give a solution of infinite dilution.

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11
Q

Infinitely dilute solution

A

There is a sufficiently large excess of water that adding any more doesn’t cause any further heat to be absorbed or evolved

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12
Q

Hydration enthalpy

A

Enthalpy change when 1 mole of gaseous ions dissolve in sufficient water to give an infinitely dilute solution. Hydration enthalpies are always negative.

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13
Q

Lattice enthalpy

A

Enthalpy change during the formation of one mole of an ionic compound from its oppositely charged gaseous ions under standard conditions.

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14
Q

Why does lattice enthalpy decrease as ions get bigger?

A

Charge remains consistent, but size:charge ratio decreases so there are weaker attractions between the cation and the anion.

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15
Q

Enthalpy change using formation data

A

Products - reactants

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16
Q

Enthalpy change using combustion data

A

Reactants - products

17
Q

Brønsted-Lowry Acid

A

PROTON DONOR

18
Q

Brønsted-Lowry Base

A

PROTON ACCEPTOR

19
Q

Strong acid

A

Is virtually 100% ionised in solution

20
Q

Weak acid

A

Doesn’t ionise fully when it is dissolved in water.