CHEM Flashcards
refers to the state in a chemical reaction wherein the concentrations of the reactants and the products remain constant
Chemical Equilibrium
Chemical equilibrium is also called as ___ ( in which the rates of the forward and reverse reactions are the same)
Dynamic Equilibrium
enables the commercial production of ammonia from combining nitrogen gas with hydrogen gas (important reaction)
Haber Process
In 1864, two Norwegian scientists proposed the law of mass action to explain why chemical equilibrium occurs
Cato Guldberg and Peter Waage
may shift in favor of either the reactants or the products depending on certain factors
Chemical equilibria
Factors that may influence chemical equilibrium
concentration, temperature, and pressure
describes the extent the reaction favors either the forward reaction or the reverse reaction at equilibrium
magnitude of K
direction of the reaction that is favored can be determined by
obtaining Q and then comparing it to K
If the reaction quotient is smaller than the equilibrium constant
reaction shifts to the right side to give the products
equilibrium constant can be derived from the partial pressures of gaseous components instead of molar concentrations
gaseous mixture at equilibrium
one of the important concepts used in our everyday life, concepts of chemical equilibrium are applied to acid-base reactions
Acid-base
compounds that have sour taste
acids
compounds that have a bitter taste and slippery feel
Bases or alkalis
most vital chemical processes in both chemical and biological systems involve acid-base reactions in ____
aqueous solutions
formed when a proton is transferred to water (as a base)
conjugate acid
formed after a proton is lost
conjugate base
involve the transfer of protons from an acid to a base
neutralization reactions
can act as both a base and an acid
Water
measures how acidic or basic a substance is ; determined using a pH paper or a pH meter to express the acidity or basicity of a solution
pH scale
helps us understand how substances can be used and handled due to their corrosiveness
pH of substance
pertains to the amount of acid per liter of solution
Concentration
different from a strong acid
concentrated acid
gives the equilibrium position of its
dissociation reaction in aqueous solution
acid strength
completely dissociated in solution at equilibrium
strong acid
partially dissociated in an aqueous solution
weak acid
acid containing one replaceable hydrogen ion
monoprotic acid
acids that have multiple protonsa
polyprotic acids
acid compounds wherein the replaceable hydrogen is always bonded to an oxygen
Oxoacids
determined by the strongest substances in terms of their acidity or basicity
strength of the solution formed by salts
break up into ions when dissolved in water
Salts or ionic compounds
contains an electrolyte which conducts electricity and allows charges to move across the two solutions without allowing the solutions to mix
Electrolysis
destruction of a metal surface
corrosion
when the cell potential is positive
galvanic
measured by its ionization constant
strength of a weak acid or weak base
occurs in anode
Reduction
occurs in cathode
Oxidation
proton-donors
acids
proton acceptors
bases
occurs in galvanic cells
Electrolysis
obtained by subtracting from the cathode half-reaction
Salt Bridge
used as a measure of concentration of a solution
pH
deals with interconversion of
electrical and chemical energy
Electrochemistry
can be determined by Handerson-Hasselbach equation
pH of a buffer solution
can be balanced by the change in oxidation state method
redox reaction
compound can be an ___ or ____
electrolyte or nonelectrolyte
produces the current obtained from cells and batteries
Spontaneous reaction