Chem #11 Flashcards

1
Q

LEO GER

A

loses electrons oxidized (+)

gains electrons reduced (-)

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2
Q

oxidation-reduction reactions

A

always occur in pairs and focus on the movement of electrons.
o Involve the transfer of electrons from one chemical species to another.

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3
Q

law of conservation of charge

A

electrical charge can neither be created nor destroyed.

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4
Q

oxidation

A

loss of electrons

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5
Q

oxidizing agent

A

causes another atom in a redox reaction to be oxidized and is itself reduced.
 Common oxidizing agents contain oxygen or similar electronegative element

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6
Q

reducing agent

A

causes another atom in a redox reaction to be reduced and is itself oxidized.
 Common reducing agents contain metal ions or hydrides (H-)

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7
Q

reduction

A

gain of electron

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8
Q

specificity about oxidizing agent and reducing agent terminology

A

These are applied specifically to the atom that loses or gains electrons.

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9
Q

changes in oxidation state in transition metal results in ____

A

change in color

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10
Q

how do formal charge and oxidation state differ?

A

Differ from formal charges in that formal charges assume equal sharing of electrons in a bond whereas oxidation numbers assume unequal sharing with more electrons going to the more EN atom.

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11
Q

oxidation numbers

A

assigned to atoms in order to keep track of the redistribution of electrons during chemical reactions.
 Can look at how many electrons are gained or lost by each atom this way.

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12
Q

what is the oxidation # of free element

A

0

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13
Q

if it gets oxidized, it is the ____ agent

A

reducing agent

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14
Q

how to balance a redox reaction

A

o Both the net charge and the number of atoms must be equal on both sides of the equation.
o Use the half-reaction method: balance the oxidation and reduction reactions separately and then add them together.

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15
Q

complete ionic equations

A

if we split the various species into all of the ions present.

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16
Q

spectator ions

A

inert ions that are present during the reaction but are not taking part in it.

17
Q

net ionic equation

A

take out spectator ions, aqueous compounds should be split into their constituent ions, but solid salts should be kept as a single entity.

18
Q

disproportionation (dismutation)

A

a specific type of redox reaction in which an element undergoes both oxidation and reduction in producing its products.
o Biological enzymes that do these reactions and redox reactions often have metals in their active sites that act as reducing agents.

19
Q

oxidation-reduction titrations

A

o Follow the movement of electrons to reach the equivalence point.
o Use indicators that change color at a particular voltage (emf) value.
o Potentiometric titration: a form of redox titration where no indicator is used. Electrical potential voltage is measured instead.

20
Q

dehydrogenases perform ____

A

oxidation

21
Q

oxidizing agents oftentimes contain ______

A

oxygen or strong electronegative element

22
Q

what are the oxidation states of the elements in HOCl

A

H: +1, O: -2, Cl: +1

O is more EN than Cl

23
Q

what are the oxidation states of the elements in NaH

A

Na: +1
H: -1

24
Q

what are the oxidation states of the elements in O2^-2

A

-1

25
Q

what are the oxidation states of the elements in OF2

A

O: +2
F: -1

26
Q

formal charge vs oxidation number

A

formal charge assumes equal division of electrons in bonds while oxidation number assumes unequal division of electrons in bonds.

27
Q

what compounds are not broken up when making complete/net ionic equations

A

anything that is not aqueous

28
Q

what is another name for a disproportionation reaction?

A

dismutation

29
Q

Potentiometric titration

A

a form of redox titration where no indicator is used. Electrical potential voltage is measured instead.

30
Q

How many moles of Fe are in iron(III) sulfate?

A

2

31
Q

Noble gases will always have an oxidation state of ___

A

0

32
Q

oxidation can also be thought of as ______

A

number of bonds to oxygen