Chapter 9 Reactions Flashcards

1
Q

H2, Pt

A

Hydrogenation

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2
Q

Hydrogenation

A

H2, Pt

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2
Q

HX

A

Reagents for hydrohalogenation (Markovnikov spatial)

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2
Q

Br2

A

Bromination

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3
Q

1) BH3•THF 2) H2O2, NaOH

A

Hydroboration-oxidation

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3
Q

Br2, H2O

A

Halohydrin formation

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5
Q

Halohydrin formation

A

Br2, H2O

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6
Q

Acid-catalyzed hydration and oxymercuration-demercuration

A

H3O+ OR 1) Hg(OAc)2, H2O 2) NaBH4

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7
Q

Reagents for hydrohalogenation (Markovnikov spatial)

A

HX

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8
Q

Anti dihydroxylation

A

1) RCO3H 2) H3O+

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9
Q

1) OsO4 2) NaHSO3

A

Syn dihydroxylation

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11
Q

1) RCO3H 2) H3O+

A

Anti dihydroxylation

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12
Q

Hydroboration-oxidation

A

1) BH3•THF 2) H2O2, NaOH

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13
Q

Bromination

A

Br2

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14
Q

Ozonolysis

A

1) O3 2) DMS

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15
Q

1) O3 2) DMS

A

Ozonolysis

17
Q

HBr, ROOR (peroxide)

A

Reagents for hydrohalogenation (anti-Markovnikov)

18
Q

H3O+ OR 1) Hg(OAc)2, H2O 2) NaBH4

A

Acid-catalyzed hydration and oxymercuration-demercuration

19
Q

Syn dihydroxylation

A

1) OsO4 2) NaHSO3

20
Q

Reagents for hydrohalogenation (anti-Markovnikov)

A

HBr, ROOR (peroxide)