Chapter 9 - Gases Flashcards
Gases
particles have greater internal kinetic energy (relative to each other) compared to any other state of matter
gases expand to fill their container
not visible to the eye
can be mixed more effectively, which is important for chemical reactions
difficult to control in open containers, density differences can be used to sort them
gases are 1000 times more empty space, so the reaction rate may be reduced
Measuring amounts of gas
mass cannot be measured due to buoyancy
volume on its own depends on the size of the container
temperature (measure of the average kinetic energy of the particles of a substance) can be measured
three types of kinetic energy = translational, rotational, vibrational
pressure can be measured as it is force per area
Pressure
pressure of a gas depends on force and area
force = collisions between molecules and sides of container
force is affected by: number of molecules, volume of container, speed of molecules (temperature), frequency of collisions
area = surface area of walls of the container
Ideal gases
particles move in straight lines until they collide with other particles
volume of the particles is practically zero compared to total volume of gas
the IMF are practically zero compared to the effect of kinetic energy so that the collisions are elastic and the particles don’t stick to each other
these criteria are met when the temperature is much higher than the boiling point, and when they are spherical particles
water is not an ideal gas
Atmospheric pressure
force of molecule collisions divided by surface area of container
pressure decreases as the altitude increases because there is less weight of air above you
current air pressure given is the pressure the environment would be at if it was at sea level
therefore, altitude must be accounted for to determine exact pressure
Calculating pressure
when the water level in a test tube is higher than the water level of the container it is in, the pressure inside the tube is lower than the pressure outside
this is because gravity is pulling down on the liquid in the test tube, increasing the volume of the gas inside
therefore, when the water level is the same, pressure outside equals pressure of the gas inside
Gas Laws
Boyle’s Law Pressure-Temperature Law Combined Gas Law Charles Law Dalton’s Law
Molar volume at SATP
T = 25 C P = 100 kPa n = 1 V = 25