Chapter 9 Enthalpy Flashcards

1
Q

What is enthalpy

A
  • measure of heat energy in a chemical system
  • chemical system -atoms ,molecules or ions making up the chemicals
  • energy stored within bonds
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2
Q

How do you calculate enthalpy change

A

reactants - products

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3
Q

what is the law of conservation of energy

A
  • energy cannot be created or destroyed
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4
Q

What happens with a chemical reaction involving an enthalpy change

A
  • system is the chemicals - reactants and prodcts
  • surrounding are apparatus and labatories whcih are not the chemical system
  • universe is everything includes both system and surroundings
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5
Q

What is an exothermic reaction

A
  • energy transferred from system to the surrounding
  • enthalpy change in negative
  • temperature of the surroundings increases as they gain energy
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6
Q

What is an endothermic reaction

A
  • energy transferred from the surroundings to the system
  • enthalpy change is potitive
  • temperature of the surroundings decreases as they lose energy
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7
Q

What is the activation energy

A
  • is the minimum amount of energy required for a reaction to take place
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8
Q

What are standard conditions

A
  • pressure - 100Kpa
  • standard temperature 298K
  • concentration - 1moldm-3
  • standard tate physical stat of the substance under standard conditions
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9
Q

What is standard enthalpy change of reaction

A
  • enthalpy change that accompanies a reaction in molar quantities expressed in a chemical equation under standard conditions all reactants and products being in their standard states
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10
Q

What is standard enthalpy change of combustion

A
  • the enthalpy change that takes place when one mole of a substance reacts completley with oxygen under standard condition al reactants and products being in their strandard states
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11
Q

What is standard enthalpy change of formation

A
  • the enthalpy change that takes place when one mole of a compound is formed from its constituent elements in their standard states under their standard states
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12
Q

What is the standard enthalpy change of neutralisation

A
  • the enthalpy change that accompanies the reaction of an acid by a base to form one mole fo H2O under standard conditions
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13
Q

What is the standard enthalpy change of formation for elements not in a compounds

A

0Kjmol-1

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14
Q

What is the specific heat capacity of a substance

A
  • energy required to raie the temperature of 1g of a substance by 1K
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15
Q

What is the specific heat capacity of water

A
  • 4.18Jg-1K-1
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16
Q

How do you calculate heat energy

A
  • energy = mass x change in temperature x4.18
17
Q

For enthalpy change of combustion why are values different to the data book

A
  • incomplete combustion
  • heat loss to surrounding
  • evaporation of alcohol from spirit burner
  • non standard conditions
18
Q

Is combustion exothermic or endothermic

A

exothermic

19
Q

What is average bond enthalpy

A

the average enthalpy change that takes place when breaking by homolytic fission 1 mol of a given type of bond in the molecules of a gaseous species

20
Q

Describe the requirements for average bond enthalpy

A
  • energy required to break bonds
  • bond enthalpies are always endothermic ]bond enthalpies always have a positive values
21
Q

What are the limitations for average bond enthalpies

A
  • there caluclated from the actual bond enthalpies from different chemical environments
22
Q

Describe bond making and bond breaking

A
  • energy required to break bonds in endothermic - positive
  • energy released when bonds formed in bond making is exothermic - negative
23
Q

What is Hess’s law

A
  • if a reaction can take place by two routes and the starting and finishing conditions are the same the total enthalpy change is the same for each route
24
Q

How do you calculate enthalpy change of combustion from Hess’s cycle

A
  • 2-1
25
Q

How do you calculate enthalpy change of formation from Hess’s cycle

A

1-2