Chapter 9 Electrolysis Flashcards
Electrolysis
A process which produces a non-spontaneous redox rxn by the passage of electrical E from a power supply through a conducting liquid
Electrolytic cell
A cell in which electrolysis occurs
Electrolyte
A chemical substance that conducts electric current as a result of dissociation into +ve and -ve charged ions, which migrate towards the -ve (cathode) and +ve terminals of an electric circuit.
Cathode
Reduction
Anode
Oxidation
Non-spontaneous rxn
A reaction which would not normally occur without the application of electrical E. It is the reverse of a spontaneous rxn which produces electrical E.
Spontaneous rxn
A rxn which occurs naturally, either in electrochemical cells or when chemicals are mixed directly. The rxn does not need to be driven by an external source of power.
Electrochemical series
A list of half-equations, written as reduction rxn, arranged in order so that the strongest oxidising agents are on the top left hand side of the list.
Reactive electrode
An electrode which is consumed in an electrochemical cell rxn
Electro-chemical cell
A device that converts chemical E into electrical E or vice versa
Brine
A concentrated sodium chloride soln
Semi-permeable membrane
A membrane that will only allow certain molecules or ions to pass through it
Electroplating
Also known as deposition, a process which uses electrolysis to deposit a layer of metal on the surface of another material