Chapter 9 Flashcards

1
Q

What is the most important factor affecting how atoms form chemical bonds?

A

The number of valence electrons in each atom involved.

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2
Q

What is an attractive force between atoms that is strong enough to enable the group to act as a unit?

A

A chemical bond

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3
Q

What is the octet rule?

A

The statement that the valence shell of an atom wants to have eight electrons.

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4
Q

Elements toward the left of the periodic table tend to ________ electrons in bonding, while elements toward the right of the periodic table tend to _________ electrons in bonding.

A

Lose

Gain

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5
Q

What is a chemical bond in which positively charged ions are electrically attracted to negatively charged ions?

A

Ionic bond

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6
Q

The elements on the ______ of the periodic table- metals -react with those elements on the far ______- nonmetals (excluding the noble gases) -to form ionic crystalline solids.

A

Left side

Far right

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7
Q

What should we associate covalent bonding with?

A

Sharing electrons

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8
Q

What is a chemical bond that results from the sharing of valence electrons between atoms?

A

A Covalent bond
The mutual attraction of both positive nuclei for the negatively charged electron cloud holds the nuclei together in a covalent bond.
Each paired electron results in a single covalent bond.

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9
Q

When two atoms share a single pair of electrons, the bond is what?

A

a Single Bond

A single covalent bond

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10
Q

When atoms share two pairs of electrons it forms a what?

A

Double bond

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11
Q

What is formed when atoms share three pairs of electrons?

A

A triple bond

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12
Q

Some substances containing covalent do not exist as discrete molecules, nor do they have the usual properties of covalent compounds, such as low melting points. These substances are known as ___________ because they are composed of billions or trillions of atoms that are bonded together into a single unit by strong covalent bonds.

A

Covalent network

Generally, covalent bonds hold atoms together in discrete molecules.

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13
Q

When two atoms share a single pair of electrons, the bond is what?

A

a Single Bond

A single covalent bond

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14
Q

When atoms share two pairs of electrons it forms a what?

A

Double bond

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15
Q

What is formed when atoms share three pairs of electrons?

A

A triple bond

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16
Q

Some substances containing covalent do not exist as discrete molecules, nor do they have the usual properties of covalent compounds, such as low melting points. These substances are known as ___________ because they are composed of billions or trillions of atoms that are bonded together into a single unit by strong covalent bonds.

A

Covalent network

Generally, covalent bonds hold atoms together in discrete molecules.

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17
Q

The chemical bonds that bind atoms together in a metal are what? Like in covalent bonds, these bonds involve in sharing, rather than the transfer of electrons.

A

Metallic bonds

The large number of freely circulating electrons gives metals their characteristic properties.

18
Q

In most cases, the what in compounds is not completely ionic, covalent, or metallic?

19
Q

A bond is considered predominantly ionic if the electronegativity difference between the two bonded atoms is greater than what number?

20
Q

A covalent bond in which both atoms share electrons equally is what?

A

A Nonpolar bond

21
Q

A covalent bond in which electrons are shared unequally between atoms is what?

A

A Polar bond

22
Q

What is only a fraction of a full charge? What are they represented by?

A

Partial charge

Represented by the lower case Delta

23
Q

What is a bond or molecule that has a negative end and a positive end? It has two poles.

24
Q

What term refers to a situation in which electrons are shared by more than two atoms?

A

Delocalization

25
What are de localized atoms?
Atoms that circulate freely instead of being bound.
26
What is a bonding situation called in which electrons are shared by more than two atoms?
Delocalization
27
What theory uses an assumption to predict the shapes of molecules?
Valence-shell electron-pair repulsion
28
What shape has four bonding pairs around the atom, 0 nonbonding pairs, the bond angles are 109.5 degrees apart, and are nonpolar or polar?
Tetrahedral
29
What shape has three bonding pairs and 1 nonbonding pair, polar, and it's bond angles are 107 degrees apart?
Trigonal pyramidal. Only the positions of atoms describe the molecule's shape. Nonbonding electron pairs repel more than bonding pairs.
30
What shape has 2 bonding pairs and 2 lone pairs, polar, and it's bond angles are 105 degrees apart?
Angular
31
What shape has 1 or 2 bonding pairs and 0 nonbonding pairs, nonpolar or polar, and it's bonding angles are 180 degrees apart?
Linear
32
What shape has 3 bonding pairs and 0 nonbonding pairs, nonpolar or polar, and it's bond angles are 120 degrees apart?
Trigonal planar
33
Whenever electrons in a covalent bond are shared unequally, the bond will be ______.
Polar
34
Determining whether or not a molecule is a _________ __________ is important for deciding what forces of attraction exist between molecules- forces that affect many properties of substances.
Polar molecule. A molecule that has a symmetrical distribution of polar bonds will have no net dipole and will be nonpolar.
35
Many properties of a substance result from forces between molecules called what?
Intermolecular forces
36
What type of close-packed unit cells do most metals assume?
Close-packed metals normally assume the hexagonal close-packing shape.
37
In what way does a liquid crystal have characteristics of both liquids and solids?
It can move freely and it can freeze.
38
What are solids that have no ordered arrangement or pattern for the particles that compose them?
Amorphous solids
39
What solid is characterized by particles arranged in a regular and repeating three-dimensional pattern?
Crystalline solids
40
What is the simplest repeating unit in a crystalline solid?
Unit cell
41
What are some unit-cell arrangements?
Simple cubic, body-centred cubic, and face-centred cubic
42
What is one of the most efficient crystal structures?
Hexagonal close packing