Chapter 8 - Periodic Table Flashcards
oxidation number
is the charge that atom would have if the compound was composed of ions
enthalpy
It is equal to the internal energy of the system plus the product of pressure and volume.
S-block oxide and hydroxides are…
basic
group I oxides interact with….
water to produce hydroxide
group I hydroxides are
heat stable but highly soluble in water
group II metal oxides and hydroxides…
are weak bases and not very soluble in water
group I halides
white crystalline solids
group I + halogen
OR
neutralisation reaction
ionic
water soluble
aqueous solutions conduct electricity
group II halides
off-white crystalline solids
mostly ionic
group II + halogen
halogens
group 7 non-metals
p-block elements
chlorine production
by electrolysis of sodium chloride
produces hydrogen and sodium hydroxide as by-product
by membrane cell or diaphragm cell technique
initial electrolyte is saturated brine
groups
same number outer shell electrons
increasing no. electrons down a group
periods
same number of shells
general trend with s-block elemnets
atomic number and atomic radius increase and ionisation energy decreases
noble gases
ns2np6
low melting and boiling points
helium, neon, argon don’t form compounds so are inert
transition metals
d-block, period 4, ,5, 6 forms at least 1 stable ion that has partially filled d subshell variety of different oxidation states catalytic activity form coloured ions ion formation is complex
transition metals as catalysts
homogeneous - interconvert readily between oxidation states
heterogeneous - solid state catalyst and gaseous phase reactants