Chapter 8 part 2 Flashcards

1
Q

single bond

A

one pair of electrons is shared

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2
Q

double bond

A

2 pairs of electrons are shared

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3
Q

triple bond

A

3 pairs of electrons are shared

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4
Q

what is the trend with bond length and number of shared electrons

A

bond length shortens as number of shared electrons increase

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5
Q

energy required to break a bond

A

endothermic

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6
Q

energy released when bond formed

A

exothermic

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7
Q

lone pair

A

pairs of electrons localized on an atom
- only on an atom

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8
Q

bonding pairs

A

pairs of electrons found in space between atoms
- shared

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9
Q

what is the difference between lone and bonding pairs

A

bonding pair is shared between two atoms while lone pair belongs only to the atom which it is assigned

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10
Q

when does a Lewis dot structure not apply

A

ionically bonded compounds

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11
Q

how are electrons shared

A

between covalent and polar covalent bonds so each atom has a noble gas like e- configuration

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12
Q

what rule applies to hydrogen

A

duet

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13
Q

what elements does the octet rule apply to

A

C, N, O, F, and sometimes other non-metallic elements in the p block

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14
Q

which Lewis dot structure will be correct when there are multiple versions

A

one with minimized formal charges

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15
Q

duet rule

A

shares 2 electrons

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16
Q

octet rule

A

surrounded by 8 electrons

17
Q

what are the rules to drawing a Lewis structure

A
  1. add valence electrons from all atoms
  2. use pair of electrons to form bond between each pair of bound atoms
  3. arrange remaining electrons to satisfy the duet and octet rule
18
Q

when is an atom more stable

A

when it is more negative

19
Q

what are reactants

A

bonds broken

20
Q

what are products

A

bonds formed

21
Q

what are some of the exceptions of the octet

A

boron
beryllium
sulfur hexafluoride

22
Q

boron exception

A

forms 3 bonds
less than 8 electrons
electron deficient

23
Q

beryllium exception

A

less than 8 electrons (2e-)
electron deficient

24
Q

sulfur hexafluoride exception

A

more than 8 electrons

25
Q

what elements have an expanded octet

A

those elements in the 3rd period and greater

26
Q

resonance

A

more than 2 valid lewis dot structure can be written

27
Q

what are some important aspects to a resonance structure

A
  • double headed arrow
  • bond lengths the same
  • resulting structure is average of resonance structure
28
Q

odd electron molecules

A
  • uncommon
  • few molecules formed from nonmetals have odd # e-
  • very reactive
29
Q

what is the difference in length between single and double bonds

A

double bonds are a little shorter than single bonds

30
Q

formal charge

A

(-)= more EN
(+)= less EN

31
Q

what are the rules to formal charge

A
  • bonds count as 1 electron
  • lone pairs count as 2 electrons
  • tend to reside on most EN atom
32
Q

what is the equation for formal charge

A

valence electrons - (# bonding electrons/2) + # lone pair electrons