Chapter 8: Covalent Bonding Flashcards

1
Q

How are the melting points and boiling points of molecular compounds different from those of ionic compounds?

A

Molecular compounds tend to have relatively lower melting and boiling points than ionic compounds

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2
Q

Covalent bond

A

A bond formed by the sharing of electrons between atoms

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3
Q

Molecule

A

A neutral group of atoms joined together by covalent bonds

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4
Q

Diatomic molecule

A

A molecule consisting of two

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5
Q

Molecular compound

A

Compound composed of molecules

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6
Q

Molecular formula

A

Chemical formula of a molecular compound

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7
Q

What is the result of electron sharing in covalent bonds?

A

Atoms attain the electron configurations of noble gases

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8
Q

How is the strength of a covalent bond related to its bond dissociation energy?

A

A large bond dissociation energy corresponds to a strong covalent bond

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9
Q

What are some exceptions to the octet rule?

A

Molecules whose total number of valence electrons is an odd number. Also molecules in which an atom has fewer or more than a complete octet of valence electrons.

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10
Q

Polyatomic ion

A

Tightly bound group of atoms that has a positive or negative charge and behaves as a unit

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11
Q

Bond dissociation energy

A

The energy required to break the bond between two covalently bonded atoms; this value is usually expressed in kJ per mol of substance

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12
Q

Resonance structure

A

Structure that occurs when it is possible to draw two or more valid electron dot structures that have the same number of electron pairs for a molecule or ion

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13
Q

How are atomic and molecular orbitals related?

A

Just as an atomic orbital belongs to a particular atom, a molecular orbital belongs to a molecule as a whole

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14
Q

Bonding orbital

A

A molecular orbital that can be occupied by two electrons of a covalent bond

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15
Q

Tetrahedral angle

A

109.5 degrees

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16
Q

VSEPR theory

A

Valence-shell electron pair repulsion theory: The repulsion between electron pairs causes molecular shapes to adjust so that the valence-electron pairs stay as far apart as possible

17
Q

Dipole interactions

A

Occur when polar molecules are attracted to one another

18
Q

Dispersion forces

A

Weakest of all molecular interactions; caused by the motion of electrons

19
Q

Hydrogen bonds

A

Attractive forces in which a hydrogen covalently bonded to a very electronegative atom is also weakly bonded to an unshared electron pair of another electronegative atom