Chapter 7-8 - Periodicity&Reactivity Trends Flashcards

1
Q

The repeating…

Define Periodicity

A

The repeating pattern of trends in physical and chemical properties which occurs across different periods in the periodic table.

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2
Q

nuclear attraction? ionisation energy?

Trends across a period

A

Nuclear charge - Increases
Shielding - Stays roughly the same
Atomic Radius - Decreases

= Nuclear Attraction - Increases

= Ionisation energy increases

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3
Q

Trends down a group

A

Nuclear Charge - Increases
Shielding - Increases
Atomic Radius - Increases

= Nuclear Attraction decreases because atomic charge and shielding cancel out

= Ionisation energy decreases

= Reactivity increases

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4
Q

The energy required to…

Define First Ionisation Energy

A

The energy required to remove one electron from each atom in one mole of gaseous atoms to form one mole of gaseous 1+ ions.

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5
Q

Give an equation to represent the First Ionisation Energy

A

X(g) ——> X+(g) + e-

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6
Q

State the factors that affect Ionisation Energy

A

Nuclear Charge
Atomic Radius
Electron Shielding

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7
Q

when an element is…

Define Disproportionation

A

When an element is simultaneously oxidised and reduced to form 2 different products

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8
Q

Metal + Oxygen

A

= Metal Oxide

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9
Q

Metal + Water

A

= Metal Hydroxide + Hydrogen

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10
Q

Metal Oxide + Water

A

= Metal Hydroxide

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11
Q

Metal + Acid

A

= Salt + Hydrogen

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12
Q

What compound can be used to neutralise acids soils?

A

Calcium Hydroxide

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13
Q

Which 2 compounds can be used to treat indigestion?

A

Magnesium Hydroxide and Calcium Carbonate

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14
Q

2 facts about of Chlorine

A

Kills Bacteria and is toxic

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15
Q

Colour of fluorine as an element

A

Pale Yellow Gas

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16
Q

Colour of Chlorine as an element

A

Pale Green Gas

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17
Q

Colour of Chlorine in water

A

Pale Green

18
Q

Colour of Chlorine in hexane (an organic solvent)

A

Pale Green

19
Q

Colour of Bromine as an element

A

Red-Brown Liquid

20
Q

Colour of Bromine in water

A

Orange (yellow-orange)

21
Q

Colour of Bromine in hexane (an organic solvent)

A

Orange (orange-red)

22
Q

Colour of Iodine as an element

A

Grey Crystals (purple vapour)

23
Q

Colour of Iodine in water

24
Q

Colour of Iodine in hexane (an organic solvent)

25
Why do the boiling points increase down group 7?
Due to the increased london forces between molecules that require more kinetic energy to overcome
26
Why does reactivity decrease down group 7?
It becomes harder to gain electrons to form 1- ions.
27
Cl2 + H2O
= HClO + HCl
28
Chlorine + cold, dilute, aqueous sodium hydroxide
= NaClO (bleach) + NaCl + Water
29
State the 3 steps to test for Halide ions
- add dilute nitric acid - add silver nitrate solution - add ammonium solution
30
Chloride positive result
White precipate formed soluble in all conc. ammonia
31
Bromide positive result
Cream precipitate formed soluble only in concentrated ammonia
32
Iodide positive result
Yellow precipitate formed Insoluble in ammonia
33
Test for carbonate ions
- add dilute acid - bubble through limewater PR- turns cloudy (CO2 formed)
34
Test for sulphate ions
- add dilute HCl - add barium chloride sol. PR- white precipitate forms (barium sulphate)
35
Test for Ammonium ions
- add sodium hydroxide - warm gently PR- ammonia gas turns red litmus paper blue
36
Cl2 + NaOH (aq) chlorine + cold, dilute sodium hydroxide
NaClO + NaCl + H2O bleach + sodium chloride + water
37
when asked about boiling points talk about...
- london forces etc..
38
when asked about reactivity talk about...
- shells/ electrons
39
Br2 + Cl- ion
no reaction as Chlorine is more reactive than Bromine so solution remains orange in cyclohexane
40
halogen reactivity
Cl2 > Br2 > I2
41
displacement reaction to confirm order of halogen reactivity
addition of Br2 (aq) to I- (aq) ions