Chapter 7 Flashcards
True or false: Formation of a solid or gas is chemical reaction.
False.
Boiling of water to steam or freezing of water to ice is not a chemical reaction.
True or false: Heat absorption, heat emission, and light emission are evidence of a chemical reaction.
True.
True or false: ice melting upon warming is chemical reaction.
False. both ice and water are H2O-no chemical change.
True or false: bubbles forming while a can of soda is opened is a chemical reaction.
False. bubbles are just carbon dioxide coming out of solution.
Ture or false: an electrical current passing through water resulting in the formation of H2 and O2 that appears as bubbles rising in water is a chemical reaction.
True because 2H2O –> 2H2 + O2
True or false: Iron rusting is a chemical reaction.
True 4Fe + 3O2 –> 2Fe2O<span>3</span>
True or False: reactants are on the right side of the equation
False
True or false: products are on the right side of the equation.
True
What does (g) indicate in the following reaction
CH4(g) + 2O2(g) –> CO2(g) + 2H2O(g)
gas phase
How are chemical equations balanced?
number of each type of atom must be equal in the reactants and products
Is the following equation balanced?
CH4(g) + O2(g) –> CO2(g) + H2O(g)
No. H and O are not equal.
Balance
SiO2(s) + C(s) –> SiC(s) + CO(g)
SiO2(s) + 3C(s) –> SiC(s) + 2CO(g)
Balance the following
a CO2 + b H2O –> c c6H12O6 + d O2
a=
b=
c=
d=
a=6, b=6, c=1, d=6
True or false: an aqueous solution is a homogeneous mixture of a substance with water.
True
True or false: a compound is soluble in a particular liquid if it dissolves in that liquid.
True
True or false: a reaction which does not for a solid when two aqueous solutions are mixed is called a precipitate.
false
What is precipitate in the following reaction and which are soluble and insoluble?
2KI(aq) + Pb(NO3)2(aq) –> PbI2(s) +2KNO3(aq)
precipitate: PbI2(s)
soluble: KI(aq), Pb(NO3)2(aq), KNO3(aq)
Insoluble: PbI2(s)
For the following molecular equation what is the complete ionic equation
AgNO3(aq) + NaCl(aq) –> AgCl(s) + NaNO3(aq)
Ag+(aq) + NO3-(aq) + Na+(aq) + Cl-(aq) –> AgCl(s) + Na+(aq) + NO3-(aq)
True or false: acid-base reactions are reactions that form water when mixing an acid and a base
true
True or false: reactions which involve transfer of electrons are called oxidation-reduction reactions and many involve a reaction of a substance with oxygen.
true
True or false: all alkali metal compounds are not soluble.
false
True or false: all Li, Na, K NH4 compounds are soluble.
True
True or false: all compounds containing NO3-, ClO3-, and ClO4- are not soluble.
False
True or false: Most OH- compunds are soluble with the exception of Alkali metals, Ba2+ and NH4+
False
True or false: Most Cl-, Br-, and I- compunds are soluble with the exception of Ag+, Hg22+, or Pb2+
True
True or false: All CO32-, PO43-, and S2- compounds are insoluble with the exception of alkali metals and NH4+
True
True or false: Most SO4 compunds are soluble with exception of Ba2+, Hg2+, Pb2+
True
What is a precipitate reaction?
a reaction that forms a solid or precipitate when two aqueous solutions are mixed.
Write the precipitate equation for sodium carbonate and copper(II) chloride.
Na2CO3(aq) + CuCl2(aq) –> CuCO3(s) + 2NaCl(aq)
Write the precipitate equation when solutions of lithium nitrate and sodium sulfate are mixed if a reaction occurs.
No reaction since NO3- is soluble with Na+ and SO42- is soluble with Li+
Write the precipitate equation when solutions of lead (II) acetate and sodium sulfate are mixed if a reaction occurs.
Pb(C2H3O2)2(aq) + Na2SO4(aq) –> PbSO4(s) + 2NaC2H3O2(aq)
Will the reaction form a precipitate?
a. NaNO3(aq) + CaS(aq)
b. MgSO4(aq) + CaS(aq)
c. NaNO3(aq) + MgSO4(aq)
a. no
b. yes MgS and CaSO4 are insoluble
c. no
What is the net ionic equation?
An equation which only shows the species that actually participate in the reaction.
What is the net ionic equation of
Ag+(aq) + NO3-(aq) + Na+(aq) + Cl-(aq) –> AgCl(s) + Na+(aq) + NO3-(aq)
Ag+(aq) + Cl-(aq) –> AgCl(s)
Write the complete ionic equation and the net ionic equation for the reaction.
Pb(NO3)2(aq) + 2 LiCl(aq) –> PbCl2(s) + 2 LiNO3(aq)
Complete: Pb2+(aq) + 2 NO3-(aq)+ 2 Li+(aq) + 2 Cl-(aq) –> PbCl2(s) + 2 Li+(aq) + 2 NO3-(aq)
Net: Pb2+(aq) + 2 Cl-(aq) –> PbCl2(s)
True or false: gas evolution reactions do not produce gas.
false
Write molecular and net ionic reaction for HNO3(aq) and CA(OH)2(aq).
Molecular: 2 HNO3(aq) + Ca(OH)2(aq) –> 2 H2O(l) + CA(NO3)2(aq)
Net ionic: 2H+(aq) + 2 OH-(aq) –> 2 H2O(l)
Write gas evolution equation for aqueous nitric acid and aqueous sodium carbonate.
2 HNO3(aq) + Na2CO3(aq) –> H2O(l) + CO2(g) + 2 NaNO3(aq)
True or false: Redox reaction include
a. a substance which reacts with elemental oxygen
b. a metal that reacts with a nonmetal
c. one substance which transfers electrons to another substance
a. true
b. true
c. true
Is 2 Mg(s) + O2(g) –> 2 MgO(s) a redox reaction?
yes, Mg reacts with elemental O2
Is 2 HBr(aq) + Ca(OH)2(aq) –> H2O(l) + CaBr2(aq) a redox reaction?
no, acid base reaction.
True or false: combustion reactions are redox reactions
true
Write balanced equation for combustion of CH3OH.
2 CH3OH(l) + 3 O2(g) –> 2 CO2(g) + 4 H2O(l)
Is Ca(s) + Cl2(g) –> CaCl2(s) a redox reaction?
yes, metal reacts with nonmetal
Is Zn(s) + Fe2+(aq) –> Zn2+(aq) +Fe(s) a redox reaction?
yes, transfer of electrons
Type of chemical reaction
a. A + B –> AB
b. AB –> A + B
c. A + BC –> AB + C
d. AB + CD –> AC + BD
a. synthesis or combination
b. decomposition
c. single displacement
d. double displacement
Complete equations and identify type of reaction
a. CaO(s) + CO2(g) –> CaCO3(s)
* b. KClO3(s)* –> KCL(s) + O2(g)
c. Na(s) + HOH(l) –> NaOH(aq) + H2(g)
d. HCl(aq) + Na2CO3(aq) –> H2O(l) + CO2(g) + NaCl(aq)
a. CaO(s) + CO2(g) –> CaCO3(s) synthesis
b. 2 KClO3(s) –> 2 KCL(s) + 3 O2(g) decomposition
c. 2 Na(s) + 2 HOH(l) –> 2 NaOH(aq) + H2(g) displacement
d. 2 HCl(aq) + Na2CO3(aq) –> H2O(l) + CO2(g) + 2 NaCl(aq) double displacement with gas evolution and acid base reaction
Which of the following are chemical reactions?
a. butane buring in a butane lighter
b. butane evaporating out of a lighter
c. wood burning
d. dry ice subliming
a. yes combustion with O2
b. no just phase change
c. yes combustion
d. no just phase change
Write balanced reaction of aqueous lead(II) acetate with aqueous potasium iodide to form solid lead(II) iodide and aqueous potasium acetate.
Pb(C2H3O2)2(aq) + 2 KI(aq) –> PbI2(s) + 2 KC2H3O2(aq)
Balance HCl(g) + O2(g) –> H2O(l) + Cl2(g)
4 HCl(g) + O2(g) –> 2 H2O(l) + 2 Cl2(g)
Which are soluble?
a. CuS
b. FeSO4
c. PbCO3
d. NH4Cl
a. no
b. yes
c. no
d. yes
Write equation for precipitation reaction that occurs (if any) when solutions of potassium hydroxide and nickel(II) bromide are mixed.
2 KOH(aq) + NiBr2(aq) –> Ni(OH)2(s) + 2 KBR(aq)
Write equation for precipitation reaction that occurs (if any) when solutions of ammonium chloride and iron(III) nitrate are mixed.
no reaction
Write complete and net ionic equation for
2 HBr(aq) + Ca(OH)2(aq) –> 2 H2O(l) + CaBr2(aq)
2 H+(aq) + 2 Br-(aq) + Ca2+(aq) + 2 OH-(aq) –> 2 H2O(l) + Ca2+(aq) + 2 Br<span>-</span>(aq)
2 H+(aq) + 2 OH-(aq) –> 2 H2O(l) or H+(aq) + OH-(aq) –> H2O(l)
Write molecular and net ionic equation for the reaction between aqueous H2SO4 and KOH
H2SO4(aq) + 2 KOH(aq) –> 2 H2O(l) + K2SO4(aq)
H+(aq) + OH-(aq) –> H2O(l)
Write equation for the gas evolution that occurs when aqueous hydrobromic acid and potassium sulfite are mixed
2 HBr(aq) + K2SO3(aq) –> H2O(l) + SO2(g) + 2 KBr(aq)
Which are redox reactions
a. 2 Li(s) + Cl2(g) –> 2 LiCl(s)
b. 2 Al(s) + 3 Sn2+(aq) –> 2 Al3+(aq) + 3 Sn(s)
c. Pb(NO3)2(aq) + 2 LiCl –> PbCl2(s) + 2 LiNO3(aq)
d. C(s) + O2(g) –> CO2(g)
a. yes
b. yes
c. no precipitation
d. yes
Write balanced equation for combustion of pentane C5H12
C5H12(l) + 8 O2(g) –> 5 CO2(g) + 6 H20(g)