Chapter 6- Thermochemistry Flashcards

1
Q

Law of Conservation of Energy

A

energy can be transformed from one form to another, but it cannot be created or destroyed

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2
Q

Potential energy

A

energy due to position or composition

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3
Q

Kinetic energy (KE)

A

energy due to the motion of an object, depends on mass and velocity

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4
Q

KE Formula

A

KE=½mv^2

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5
Q

Temperature

A

property that reflects random motion of particles in a particular substance

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6
Q

Heat (q)

A

involves the transfer of energy between 2 objects due to difference in temperature

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7
Q

Work (w)

A

force acting over a distance

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8
Q

State Function

A

property of a system that depends only on its present state, and is independent of the particular pathway

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9
Q

Exothermic

A

chemical reaction that results in an evolution of heat, energy is flowing out of the system

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10
Q

Endothermic

A

chemical reaction that absorbs energy, and flows into the system

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10
Q

Endothermic

A

chemical reaction that absorbs energy, and flows into the system

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11
Q

Enthalpy (H)

A

property of a system that measures the system’s ability to allow heat or energy to flow through

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12
Q

Formula of enthalpy change

A

H=E+PV

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13
Q

+H, +q, +w, compressed gas, -volume

A

Reaction is endothermic

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14
Q

-H, -q, -w, expanding gas, +volume

A

Reaction is exothermic

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15
Q

Calorimetry

A

measuring heat and is based on observing temperature change

16
Q

Heat Capacity (C) formula

A

heat absorbed /increase in temperature

17
Q

Specific heat capacity (s)

A

energy required to heat 1g of a substance

18
Q

Heat formula

A

q=smT

19
Q

1st law of thermodynamics

A

energy of the universe is constant

20
Q

Internal energy

A

the sum of the kinetic and potential energy of all particles in the system

21
Q

Internal energy formula

A

E=q+w

22
Q

Formula for work

A

w=-PV

23
Q

1 L*atm=

A

101.325 J

24
Q

Energy

A

to do work or produce heat

25
Q

Hess’s law

A

enthalpy change is the same regardless if the reaction took many steps or one step

26
Q

Standard enthalpy of formation

A

enthalpy change that accompanies the formation of one mole of a compound from its elements, with all substances in their standard states

27
Q

Standard enthalpy of formation formula

A

nH(products)-nH(reactants)

28
Q

CH4

A

Methane

29
Q

C2H6

A

Ethane

30
Q

C2H6

A

Propane

31
Q

C4H10

A

Butane

32
Q

C5H12

A

Pentane

33
Q

C6H14

A

Hexane

34
Q

C7H16

A

Heptane

35
Q

C8H18

A

Octane