chapter 6: ionic bonding Flashcards

1
Q

What are noble gases?

A
  • noble gases are monatomic
    > exists as individual atoms
    > stable and unreactive
  • do not usually react with other elements to form compounds
  • elements of group 0: Helium (He)
    , Neon (Ne)… etc
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2
Q

How do atoms achieve the electronic configuration of noble gases?

A
  • atoms of elements (except for noble gases), do not have fully filled outer shells
  • they are reactive
    > undergo reactions to achieve stable electronic configuration of a noble gas
    1. Losing outer electrons
    2. Gaining outer electrons
    3. Sharing outer electrons
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3
Q

READ AND UNDERSTAND!
- atom becomes an ion if it loses or gains electrons
> number of protons and electrons are different
> ions carry a positive charge or a negative charge
- metals form positively charged ions ( cations) and non-metals form negatively charged ions (anions)

A

The chapter you’re learning today is going to save someone’s life tomorrow. So pay attention.

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4
Q

What is 1. duplet electronic configuration and
2. octet electronic configuration?

A

1.has two outer electrons
>helium
2. Atoms of noble gases have 8 outer electrons

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5
Q

How are positive ions formed?

A
  • cations formed when atoms lose electrons
  • atoms of metals generally only have a few outer electrons
    > tend to lose electrons to form cations
  • when an atom loses electrons, it has more protons than electrons
    > positive ion
  • the charge on a cation corresponds to the number of electrons the atom loses
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6
Q

How are negative ions formed?

A
  • anions formed when atoms gain electrons
    > generally, non-metals have more than 4 outer electrons
    > tend to gain electrons to form anions
    >more electrons than protons
    >anion is formed
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7
Q

Draw a dot diagram of
1. Chlorine atom > _______ ion
2. Oxygen atom > _______ ion

A
  1. Chloride ion
  2. Oxygen ion

Look at page 93 of textbook

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8
Q

What are ionic bonds?

A
  • are the strong electrostatic forces of attraction between positive and negative ions
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9
Q

Draw a dot-and-cross diagram of the formation of sodium chloride.

A

Things to remember when drawing:

Page 97

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10
Q

Draw a dot-and-cross diagram of the formation of magnesium chloride.

A

Things to remember when drawing:

Page 97

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11
Q

Draw a dot-and-cross diagram of
1. Sodium atom > sodium ion
2. Magnesium atom > magnesium ion

A

Refer to page 92 of tb :)

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12
Q

what are polyatomic ions and what are some examples of it?

A
  • ions composed of two or more covalently bonded atoms
    eg: ammonium ion (NH₄⁺), carbonate ion (CO3 2-), sulfate ion ( SO₄²-)
    pg 95 of tb :)
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13
Q

turn to page 97 & 98 on general rules for chemical formulae of ionic compounds

A

yes

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14
Q

how do we deduce the chemical formula of an ionic compound?

A
  • all the positive charges must be equal to the negative charges in an ionic compound
    > construct the formula of an ionic compound by balancing the charges on the positive ions with those on the negative ions
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15
Q

deduce the chemical formula of :
(i) calcium chloride
(ii) aluminium oxide
(iii) magnesium oxide
(iv) copper (II) hydroxide
(v) ammonium sulfate
(vi) calcium carbonate

A

(i) calcium chloride: CaCl2
(ii) aluminium oxide: Al₂O₃
(iii) magnesium oxide: MgO
(iv) copper (II) hydroxide: Cu(OH)₂
(v) ammonium sulfate: (NH₄)₂SO₄
(vi) calcium carbonate: CaCO3

page 99 of tb :)

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16
Q

what is the formula of these cations?
1. ammonium
2. copper (II)
3. iron (III)
4. chromium (III)

A
  1. NH₄⁺
  2. Cu 2+ (2+ on top)
  3. Fe 3+ (3+ on top)
  4. Cr 3+ (3+ on top)
17
Q

what is a giant ionic lattice structure?

A
  • it is a three dimensional network of ions
  • ions packed together in a regular and repeating pattern
  • giant lattice structure held together tightly together and ions held in fixed positions
    > cuz the oppositely charged ions attract one another strongly

pg101

18
Q

how can we deduce the formula of sodium chloride from its lattice structure?

A
  • To deduce the formula
    > can determine the ratio of sodium ions to chloride ions in a formula unit
    in lattice structure of sodium chloride:
  • each Na+ ion is surrounded by six Cl- ions
    -each Cl- ion is surrounded by six Na+- ions
  • the overall ration of sodium ions to chloride ions is 1:1
  • formula of sodium chloride: NaCl
19
Q

What are the physical properties of ionic compounds?

A
  1. most ionic compounds have high melting and boiling points
    - in ionic compounds, the forces of attraction between oppositely charged ions > strong
    - large amount of heat is needed to overcome the strong forces of attraction to melt the ionic compound
    - due to high b.p and m.p
    > most ionic compounds are solids at room temperature and pressure
    > ionic compounds are non volatile
  2. are usually soluble in water and insoluble in solvents
    > usually soluble in water BUT ionic compounds like
    > silver chloride and barium sulfate is insoluble in water
    - insoluble in organic solvents such as:
    >oil, petrol, turpentine
  3. conduct electricity when molten or in aqueous solution ( dissolved in water)
20
Q

why are most ionic compounds soluble in water and insoluble in solvents?

A
  • water molecules are attracted to ions
    > weakens the electrostatic forces between the ions
    > ions pulled from the lattice structure compound dissolves to form an aqueous solution
  • in organic solvents, no water present
    > insoluble in them and remain tightly held in the lattice structure
21
Q

why do ionic compounds conduct electricity when molten or dissolved in water? but not in solids?

A
  • there must be free moving ions or electrons in order to conduct electricity
  • when it is molten or dissolved in water to form an aqueous solution
    > cations and anions are free to move and are able to conduct electricity
  • however, there are no free moving ions to conduct electricity in the solid state since the ions are held in place in the lattice structure
22
Q

what are the formula of these anions:
1. hydrogen carbonate
2. hydroxide
3. nitrate
4. carbonate
5. sulfate
6. phosphate

A
  1. HCO3 - ( - on top)
  2. OH - ( - on top)
  3. NO3 - ( - on top)
  4. CO3 2- ( 2- on top)
  5. SO4 2- ( 2- on top)
  6. PO4 3- ( 3- on top)
23
Q

what do chemical formulas show?

A

the number of atoms and the type of elements in a compound

24
Q

what are the chemical formulas for the following acids:
1. Hydrochloric acid
2. nitric acid
3. Phosphoric acid
4. Sulfuric acid

A
  1. HCl
  2. HNO3
  3. H3PO4
  4. H2SO4