Chapter 6- Ionic and Molecular Compounds Flashcards
Ionic bonds
occur when the valence electrons of atoms of a metal are transferred to atoms of a nonmetal.
Covalent bonds
form when atoms of nonmetals share valence electrons.
Ionic and Covalent Bonds
Chemical bonds are formed when atoms lose, gain, or share valence electrons to acquire an octet of eight valence electrons (octet rule).
Positive Ions: Metals Lose Electrons and form Cations
Sodium atoms in Group 1A (1) are neutral, with 11 electrons and 11 protons. They
•lose one electron to have the same number of valence electrons as neon and a filled energy level
•will form an ion with 10 electrons and 11 protons, and an ionic charge of 1+, Na+
Negative Ions: Gain of Electrons to form Anions
Chlorine atoms in Group 7A (17) are neutral, with 17 electrons and 17 protons. They
•will gain one electron to have the same number of valence electrons as argon and a filled energy level
•form an ion with 18 electrons and 17 protons, and an ionic charge of 1−, Cl−
Write the formula and symbol of an ion with 16 protons and 18 electrons.
The element with 16 protons is sulfur, with the symbol S. An ion of sulfur with 18 electrons gives sulfur a chargeof 2−. The sulfide ion is
S -2
Consider the elements calcium and chlorine.
A. Identify each as a metal or a nonmetal.
B. State the number of valence electrons for each.
C. State the number of electrons that must be lost or gained for each to acquire an octet.
D. Write the symbol, including its ionic charge, and name of each resulting ion.
A. Identify each as a metal or a nonmetal.calcium = metalchlorine = nonmetal
B. State the number of valence electrons for each.Calcium in Group 2A (2) has two valence electrons.Chlorine in Group 7A (17) has seven valence electrons.
C. State the number of electrons that must be lost or gained for each to acquire an octet.Calcium will lose two electrons to acquire an octet.Chlorine will gain one electron to acquire an octet.
D. Write the symbol, including its ionic charge, and name of each resulting ion.
Ca2+ Calcium
Cl- Chloride
Ionic Compounds
- consist of positive and negative ions
- have attractions called ionic bonds between positively and negatively charged ions
- have high melting points
- are solid at room temperature
Write the ionic formula for the compound formed with Ba2+and Cl− ions.
Write the symbols of the ions:
Ba2+ Cl−Cancel the positive and negative charges.Cross multiply the numbers.
Writing the cation first and the anion second gives the formula BaCl2.
Select the correct formula for each of the following ionic compounds:
A. Na+ and O2−
1. NaO 2. Na2O 3. NaO2
B. Al3+ and Cl−
1. AlCl3 2. AlCl 3. Al3Cl
C. Mg2+ and N3−
1. MgN 2. Mg2N3 3. Mg3N2
A. Na+ and O2−
Ans: 2. Na2O
B. Al3+ and Cl−
Ans:1. AlCl3
C. Mg2+ and N3−
Ans: 3. Mg3N2
Naming Ionic Compounds
When naming an ionic compound,
•the name of the metal is written first and is the same as the name of the element
•the name of the nonmetal is the first syllable of the nonmetal name + ide ending and is written second
•a space is placed between the names of the metal and nonmetal ion
Write the names for the following compounds:
A. CaO Fill in the blank
B.Al2S3 Fill in the blank
C.MgCl2 Fill in the blank
Step 4 Write the name for the cation first and the name for the anion second.
A. The name of CaO is calcium oxide.
B. The name of Al2S3 is aluminum sulfide.
C. The name of MgCl2 is magnesium chloride.
Metals with Variable Charges
Transition elements except for Zn2+, Cd2+, and Ag+ form two or more positive ions (cations). We say they have variable charge.
A Roman numeral equal to the ion charge is placed in parentheses immediately after the metal name.
Use the charge on the anion and charge balance to calculate charge on the metal ion.
MnF2
Therefore, the name of MnF2 is Manganese (II) fluoride.
Naming Ionic Compounds with Variable Charge Metals
Name the ionic compound FeCl2
STEP 1 Determine the charge of the cation from the anion.
Fe2+
STEP 2 Name the cation by its element name and use a Roman numeral in parentheses for the charge.
Iron (II)
STEP 3 Name the anion by using the first syllable of its element name followed by ide.
chloride
STEP 4 Write the name for the cation first and the name for the anion second.
Iron(II)Chloride
Name the following ionic compound containing a variable charge metal: MnO2
STEP 1 Determine the charge of the cation from the anion.
STEP 2 Name the cation by its element name and use a Roman numeral in parentheses for the charge.
Manganese (IV)
STEP 3Name the anion by using the first syllable of its element name followed by ide. oxide
STEP 3Name the anion by using the first syllable of its element name followed by ide. oxide
Manganese (IV) Oxide
Write the formula for SnCl2
tin(II)chloride
Write chemical formulas for the following compounds:
A. Nickel(II)sulfide
B. Zinc Chloride
C. Iron(III)Oxide
STEP 3 Write the formula, cation first, using subscripts from the charge balance.
A. NiS
B. ZnCl2
C.Fe2O3
Polyatomic Ions
- are a group of atoms with an overall charge
- often consist of a nonmetal such as phosphorus, sulfur, carbon, or nitrogen covalently bonded to oxygen atoms
- usually have a 1−, 2−, or 3− charge
- have a negative charge except for NH4+, ammonium, which has a positive charge
Writing Formulas for Compounds Containing Polyatomic Ions
When writing formulas for ionic compounds containing polyatomic ions, we use the same rules of charge balance as those for simple ionic compounds.
Consider the formula for magnesium nitrate:
Mg(NO3)2
Write the formula for aluminum bicarbonate.
Al (HCO3)3
Write the formula for sodium phosphate.
Na 3 PO 4
Write the correct formula for each compound. A. aluminum nitrate B. copper (II) nitrate C. iron (III) hydroxide D. tin (IV) hydroxide
A. Al(NO3)3
B. Cu(NO3)2
C. Fe(OH)3
D. Sn(OH)4
Name the following ionic compounds:
A. Ca(NO3)2
B. SnSO4
A. Calcium nitrate
B. tin(II)Sulfide
Name the following ionic compounds:
A. MgSO3
B.MgSO4
C. Pb3(PO3)2
A. Magnesium sulfite
B. Magnesium sulfite
C. lead(II)Phosphite
Molecular Compounds: Sharing Electrons
Learning Goal Given the formula of a molecular compound, write its correct name; given the name of a molecular compound, write its formula.
The names of molecular compounds need prefixes because several different compounds can be formed from the same two nonmetals.
When naming a molecular compound:
- the first nonmetal in the formula is named by its element name
- the second nonmetal is named by using the first syllable of its name followed by ide
When a subscript indicates two or more atoms of an element, a prefix is used in front of its name.
Select the correct name for each molecular compound:
A. SiCl4
B. P2O5
C. Cl2O7
A. silicon tetrachloride
B. diphosphorus pentaoxide
C. dichlorine heptoxide
Identify each compound as ionic or molecular, and give its correct name. A. SO3 B. BaCl2 C. (NH4)3PO3 D. Cu2CO3 E. N2O4
A. SO3 molecular, sulfur trioxide
B. BaCl2 ionic, barium chloride
C. (NH4)3PO3 ionic, ammonium phosphite
D. Cu2CO3 ionic, copper(I) carbonate
E. N2O4 molecular, dinitrogen tetroxide
Lewis Structures for Molecules
Learning Goal Draw the Lewis structures for molecular compounds with single and multiple bonds.
Lewis structures use Lewis symbols to diagram the sharing of valence electrons for single and multiple bonds in molecules.
o draw the Lewis structure for a fluorine molecule, F2,
- we start with two fluorine atoms each with seven valence electrons
- each fluorine atom shares one electron to form a covalent bond, giving each fluorine an octet
Drawing Lewis structures
- To draw the Lewis structure for methane, CH4, we start by drawing the Lewis symbols for carbon and hydrogen.
- Carbon needs four hydrogen atoms to complete the noble gas configurations for carbon and hydrogen.
Draw the Lewis structure for the following-
A. PF3
B. H2S
C. CCl4
on slide 63
Diatomic Molecules
The elements hydrogen, nitrogen, oxygen, fluorine, chlorine, bromine, and iodine exist as diatomic molecules.
There are seven diatomic molecules: H2, N2, O2, F2, Cl2, Br2, and I2.
electronegativity
The electronegativity value of an element indicates the attraction of an atom for the shared electrons in a bond.
Electronegativity
•increases from left to right going across a period on the periodic table
•increases from the bottom to the top of the periodic table
•is high for the nonmetals, with fluorine as the highest
•is low for the metals
nonpolar covalent bond
A nonpolar covalent bond
•occurs between nonmetals
•is an equal or almost equal sharing of electrons by two bonding atoms
•has a very small electronegativity difference
examples:
N-N 3.0 − 3.0 = 0.0 Nonpolar covalent
Variations in Bonding -
electronegativity
The difference in electronegativity values for two atoms can be used to predict the type of chemical bond.
•If the electronegativity difference is between 0 and 0.4, the bond is nonpolar covalent.
•If the electronegativity difference is between 0.5 and 1.8, the bond is polar covalent.
•If the electronegativity difference is between 1.9 and 3.3, the bond is ionic.
polar covalent bond
A polar covalent bond •occurs between nonmetal atoms •is an unequal sharing of electrons •has a moderate electronegativity difference O---Cl 3.5 − 3.0 = 0.5 Polar covalent