Chapter 6 Common Nuceophile

Question 0

What are the common Nitrogen nucleophiles?

Answer 0

Ammonia

Amines

Question 1

What are the common oxygen nuceophiles?

Answer 1

Hydroxide
Alkoxide 
Water
Alcohol
Carboxylate

Question 2

What are the common sulfur nuceophiles?

Answer 2

Hydrosulfide
Mercaptide
Thioether

Question 3

What are the common Halogen nucleophiles?

Answer 3

Iodide

Question 4

What are the common Carbon nucleophiles?

Answer 4

Cyanide

Acetylide

Question 5

Water + R =

Answer 5

Alkyloxonium ion

Question 6

Hydroxide + R =

Answer 6

Alcohol

Question 7

Alkoxide + R =

Answer 7

Ether

Question 8

Alcohol + R =

Answer 8

Dialkyloxonium ion

Question 9

Carboxylate + R =

Answer 9

Ester

Question 10

Hydro sulfide + R =

Answer 10

Thiol

Question 11

Mercaptide + R =

Answer 11

Thioether

Question 12

Thioether + R =

Answer 12

Trialkylsulfonium

Question 13

Iodide + R =

Answer 13

Alkyl iodide

Question 14

Sn2 mechanism

Answer 14

One step process,

Nucleophile + substrate-> transition state-> product + Leaving group

Question 15

Sn1 mechanism

Answer 15

Two step process,
Substrate–> (slow) carbocation + leaving group

Carbocation + nucleophile–> (fast)

Question 16

E2 mechanism

Answer 16

Is a process in which HX is eliminated and a C==C bond is formed in the same step

Question 17

E1 mechanism

Answer 17

Is a two-step process with the same first step as an SN1 reaction, and product like E2

Question 18

Alkoxide

Answer 18

RO(-)

Question 19

Hydrosulfide

Answer 19

HS(-)

Question 20

Mercaptide

Answer 20

RS(-)

Question 21

Thioether

Answer 21

R2S

Question 22

Cyanide

Answer 22

(-) C{triple}N

Question 23

Acetylide

Answer 23

(-)C{triple}CR