Chapter 6-9 Exam Flashcards
Three states of water:
solid (ice), liquid (liquid water), and gas (water vapor)
the most prevalent state on Earth.
Liquid water
The ___ shape of the ____ molecule causes it to be ____, acting like a ____ magnet. This characteristic leads to many unique properties including _______.
The angular shape of the water molecule causes it to be polar, acting like a weak magnet. This characteristic leads to many unique properties including the ability of water to dissolve many salts.
In a _____, the atoms of oxygen and hydrogen share the energy of paired electrons
Covalent bond
When a hydrogen atom in one water molecule is attracted to the oxygen atom of an adjacent water molecule, a _____ forms.
hydrogen bond
A _____ bond is much stronger than a ____ bond.
covalent, hydrogen
Water molecules in ice are held together by ______ in a rigid matrix in which the _________. Density of ice at 0oC is 0.917 g/cm3 (i. e., ice floats in water).
Water molecules in ice are held together by hydrogen bonds in a rigid matrix in which the molecules are farther apart than in liquid water, causing ice to be less dense than liquid water. Density of ice at 0oC is 0.917 g/cm3 (i. e., ice floats in water).
______ is a powerful solvent. It dissolves more substances in greater quantities than any other common liquid due to the polar nature of the water molecule, which is caused by its angular shape.
Water is a powerful solvent. It dissolves more substances in greater quantities than any other common liquid due to the polar nature of the water molecule, which is caused by its angular shape.
To evaporate water into water vapor, all _____ have to be broken, requiring much ______ input (540 calories per gram).
To evaporate water into water vapor, all hydrogen bonds have to be broken, requiring much energy input (540 calories per gram).
Freezing temperature of pure water is ____ and boiling temperature of pure water is ____
Freezing temperature of pure water is 0 oC and boiling temperature of pure water is 100 oC.
_____ and _____ points are unexpectedly high compared with molecules of similar molecular structure.
Boiling and melting points are unexpectedly high compared with molecules of similar molecular structure.
Pure water has a density maximum at ____, and typical sea water has a density maximum at ____ (freezing temperature of sea water).
Pure water has a density maximum at 3.98oC, and typical sea water has a density maximum at -2oC (freezing temperature of sea water).
Adding ____ to water decreases the freezing point, much like antifreeze keeps your radiator water from freezing.
Adding salt to water decreases the freezing point, much like antifreeze keeps your radiator water from freezing.
1 cm3 of pure freshwater weighs ___ gram at 4 oC, the temperature of _____ density.
1 cm3 of pure freshwater weighs 1 gram at 4 oC, the temperature of maximum density.
The heat capacity is the heat required to raise the temperature of 1 gram of a substance by 1 oC. The ocean is slow to heat up and slow to cool down due to its high heat capacity. Land is heated (or cooled) much quicker than the ocean. Thus, the local ocean has a moderating effect on local climate.
For water, the latent heat of evaporation or vaporization is larger (540 calories per gram) than the latent heat of melting (80 calories per gram). It takes a total of 100 calories to raise the temperature of 1gram of freshwater from 0 to 100 oC.
Know how to figure total calories needed to change 1 gram of ice at 0 oC to water and then to water vapor. (See figures discussed in lecture).
The thermocline is a layer in which a rapid vertical temperature change occurs. Halocline is a layer in which a rapid vertical salinity change occurs. Pycnocline is a layer in which a rapid vertical density change occurs. Lightest (most buoyant) water is above pycnocline.
The thermocline is a layer in which a rapid vertical temperature change occurs. Halocline is a layer in which a rapid vertical salinity change occurs. Pycnocline is a layer in which a rapid vertical density change occurs. Lightest (most buoyant) water is above pycnocline.
The ocean is density stratified. It can be divided into three layers: (1) surface zone, (2) thermocline/ pycnocline, (3) deep zone. The surface zone is in contact with the atmosphere and is usually well-mixed due to the action of wind and waves. The deep zone is separated from the surface zone by the thermocline except in the high latitudes where water temperature is fairly constant surface to bottom! Although, recent rapid melting of ice in polar regions is changing that! The bulk of the global ocean water (~90%) is found in the deep zone and has a relatively narrow range for its temperature and salinity.
Away from continental margins in deep water, the thermocline extends from about 100m to 1000m. In deep water the thermocline controls the pycnocline. In continental shelf areas where river discharge is prevalent, the pycnocline may be more controlled by the halocline.
How is water density affected by temperature and salinity?
When temperature decreases, density increases. When salinity increases, density increases.
Sea surface salinity distribution: Near the equator due to prevalent rainfall, precipitation exceeds evaporation causing salinity to be relatively low. Near the mouths of large rivers, salinity is low. In the large high pressure systems (30 degrees N & S), precipitation is low relative to evaporation, resulting in high salinity. In the polar regions, salinity tends to be low in summer mainly due to the melting of sea ice.
If evaporation exceeds precipitation, salinity increases. If sea ice forms, the salinity of the surrounding water increases initially, but salinity decreases when the denser salinity-laden water sinks. Salt is left behind both when water freezes and water evaporates.
What are the major physical processes that control evaporation?
(Hint: What is wind speed and humidity gradients between surface and air at 10 meters)
The latent heat that is transferred with water vapor during evaporation is released
during condensation of water vapor into droplets/rain, which intensifies tropical cyclones!
What is a maritime and continental climate?
Water is very dense compared to air. At the Earth’s surface, human’s experience ~ 1 atmosphere of pressure. As one moves down in the water column, pressure increases rapidly. Every 10 m increase in water depth, causes a pressure increase of 1 atmosphere (1 kg/cm2 increase in pressure or 14.22 lbs/in2 ).
Water is very dense compared to air. At the Earth’s surface, human’s experience ~ 1 atmosphere of pressure. As one moves down in the water column, pressure increases rapidly. Every 10 m increase in water depth, causes a pressure increase of 1 atmosphere (1 kg/cm2 increase in pressure or 14.22 lbs/in2 ).
Seawater (and freshwater) absorbs incoming visible light, as it is transmitted downwards. Water is especially effective at absorbing red wavelengths, the longer end of the spectrum, which is absorbed in the top few meters of the sea surface. Clear open ocean waters have maximum transparency in the blue region, which means it is transmitted to deeper depths.
What is a secchi disk (dates back to 1800s) and what is it used for?
Less than 1 % of the light (all wavelengths) penetrates down to 100 meter depth in the clearest ocean waters. Photosynthesis takes place in this zone which is called the euphotic zone.
Refraction changes the direction of light and sound wave propagation in the ocean, when the waves move through or into an area of different density. Sea water is very transparent to sound. Underwater sound speed (~ 1500 m/s) depends on temperature and pressure. The SOFAR (Sound fixing and ranging) channel is a channel of minimum sound velocity at about 1000 meters deep. Sound is trapped in the SOFAR channel because when it tries to escape it is refracted back into it. Sound can propagate over long distances in the SOFAR channel. Thus, it is a very effective region for communication of marine animals for long distance. If sound travels towards a local maximum in sound speed, it refracts away from the zone and a shadow zone is created and submarines can hide out there!
- The six most abundant (by weight) ions in sea salts are; Chloride (Cl-), Sodium (Na+), Sulfate (SO4–), Magnesium (Mg++), Calcium (Ca++), and Potassium (K+). Which two make Epsom Salt? Which salt is most abundant?
- Salinity refers to the total amount of dissolved solids or salts in ocean water.
- Salinity of a typical sea water is close to 35 parts per thousand (35 g of salts in 1 kg of seawater).
- Weathering of rocks on land and outgassing through volcanoes and near mid-ocean ridges are the sources of the ocean’s salts.
What is advection? What is diffusion?
*Although salinity might vary in different parts of the ocean, the ratio of major salts or solids in seawater in the ocean is constant. This is referred to as the Principle of constant proportions or Forchammer’s principle.
- Salinity used to be determined by measuring chlorinity, total amount of chloride ions. In the digital age, it can be more conveniently determined by measuring electrical conductivity of seawater. Units of ‘ppt’ are used for chlorinity measurements and ‘psu’ for conductivity measurements. The latter means “practical salinity units”. Sometimes the units are omitted since it is a ratio.
- Residence time is the average length of time an atom spends in the ocean. Residence time of all the major salts are estimated to be very long. Residence time of gases and nutrients are much shorter as they are used in biological processes.
Photosynthesis in sea water increases concentrations of O2 and decreases concentrations of CO2, while respiration increases concentrations of CO2 and decreases concentrations of O2 . Below photic zone, oxygen decreases because photosynthesis is not occurring and due to uptake by animals and bacteria during decomposition of organic material.
What is a neutral pH? Is lower than neutral pH referred to as acidic or alkaline (also called basic)?
pH is a measure of ________. One unit of pH is a change in H+ ions of _________.
- Sea water is normally mildly alkaline (about pH 8), because of the carbon dioxide dissolved in it and the 3 main reactions that take place. At normal pH for seawater, bicarbonate ions are most prevalent. When pH drops (when carbon dioxide added), reactions tend to favor dissolving CaCO3 (shells or organisms, corals) and when pH rises, precipitation of CaCO3 is favored. Study the graphic that shows these reactions!
Dissolved inorganic carbon (from carbon dioxide) enhances the ocean’s buffering capacity, usually preventing broad swings of pH when acids or bases are introduced.
Dissolved inorganic carbon (from carbon dioxide) enhances the ocean’s buffering capacity, usually preventing broad swings of pH when acids or bases are introduced.
The ocean is a large sink for which gas, thus very involved in understanding the “global warming”?
The ocean is a large sink for which gas, thus very involved in understanding the “global warming”?