Chapter 5 : Oxydation number Flashcards
Oxidation number
The charge the atom would have in a molecule (or an ionic compound) if e- were completely transfered.
Oxidation
A species is oxidized when it loses one or more e-, and its calles a reducing agent.
Reduction
a species is reduced when it gains 1 or more e-, and its called an oxidizing agent.
Oxidation and reduction
always occur together, never in isolation. If something gains e-, something else had to loose them.
free elements (uncombined state) have an oxidation number of 0
Na, Be, K, Pb, H2,O2,P4
Monoatomic ion
The oxitation number is equal to the charge of the ion.
Li+=Li=+1, Fe3+=Fe=+3, O2-=O=-2
Exception
H2O2=-1, O2=-1
Oxidation of H
The oxidation of hydrogen is +1, except when its bonded to metals in binary compounds, called metal hybrides. In these cases, its oxidation number is -1 (NaH, CaH2).
Group IA
+1
Group IIA
+2
Fluorine
-1
When its equal to 0
The sum of the oxidation numbers of all the atoms in a molecule or ion is equal to 0 or the charge of the ion.
When oxidation ?
An atom is oxidised when its oxidation number increase.
When reduced ?
An atom is reduced when its oxidation number decrease.