Chapter 5: Lipids Flashcards
Lipids (5)
- triglycerides
- phospholipids
- sterols
- carbon, oxygen, and hydrogen
- hydrophobic
Functions of lipids (6)
- store and provide energy
- insulation
- manufacture steroids and bile
- transport fat-soluble nutrients in blood
- manufacture sex hormones
- structure of cell membranes
Fatty acids (2)
- triglycerides and phospholipids
- chain of carbon and hydrogen atoms with a carboxyl group at alpha end and metal group at omega end
Fat
- more kcal than carbs and proteins because of higher ratio of carbon and hydrogen to oxygen
- 9 kcal/g
Fatty acids vary in..(3)
- length of carbon chain
- degree of saturation
- shape
Length of fatty acids (3)
carbon length of fatty pics 2 to 80 carbons long
- most common 12 to 24 carbons
- short chain, medium chain, long chain
Short-chain fatty acids
2 to 4 carbons
Medium-chain fatty acids
6 to 10 carbons
Long-chain fatty acids (2)
12 or more carbons
- most common and take longer time to digest
2 carbon, zero double bond
butyric acid
14 carbon, zero double bond
palmitic acid
18 carbon, 1 double bond
oleic acid
18 carbon, 2 double bond
linoleic acid
18 carbon, 3 double bond
alpha-linolenic acid
Degree of saturation of fatty acids
determined by whether carbons are held together by double or single bond
Saturated fatty acids (5)
- all carbons on fatty acids are bound to hydrogen
- no double bonds
- solid at room temperature
- higher melting point
- tighter structure
Unsaturated fatty acids (6)
- carbons on fatty acids form a double bond with each other, instead of binding to hydrogen
- Monounsaturated fatty acid (MUFA)
- Polyunsaturated fatty acid (PUFA)
- liquid at room temperature
- lower melting point
- looser structure
Monounsaturated fatty acid (MUFA)
one double bond
Polyunsaturated fatty acid (PUFA)
two or more double bonds
Rancidity (3)
- spoiling of fats through oxidation
- double bonds are less stable than single bonds
- unsaturated fats become rancid father
How to reduce fatty acid rancidity (3)
- antioxidants
- limit exposure to oxygen, heat, and light
- hydrogenation
Location of double bond
location of first double bond from methyl (or omega) end of unsaturated fatty acids effects properties of fatty acids
Omega-3 fatty acid
first double bond is between third and fourth carbons from omega end
- ex. alpha-linolenic acid
Omega-6 fatty acid
first double bond is between sixth and seventh carbons from omega end
- ex. linoleic acid
Shape of fatty acids
unsaturated fatty acids have two shapes based on position of hydrogen atoms around double bond
- cis form and trans form
Cis form (2)
hydrogens on same side of double bond
- boat structure
Trans form
hydrogens on opposite sides of double bond
Structure of triglyceride
glycerol backbone + three fatty acids
Triglycerides (3)
- most common lipid
- 95% of lipids
- 3 fatty acids connected to glycerol backbone
Triglycerides functions (4)
- add texture to baked goods
- make eats tender
- preserve freshness
- stored as adipose tissue for energy
Phospholipids (4)
- glycerol backbone, two fatty acids, a phosphate group, and nitrogen-containing compounds
- hydrophilic tails
- hydrophobic head
- make up phospholipid bilayer in cell membrane