Chapter 5: Lipids Flashcards

1
Q

Lipids (5)

A
  • triglycerides
  • phospholipids
  • sterols
  • carbon, oxygen, and hydrogen
  • hydrophobic
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2
Q

Functions of lipids (6)

A
  • store and provide energy
  • insulation
  • manufacture steroids and bile
  • transport fat-soluble nutrients in blood
  • manufacture sex hormones
  • structure of cell membranes
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3
Q

Fatty acids (2)

A
  • triglycerides and phospholipids

- chain of carbon and hydrogen atoms with a carboxyl group at alpha end and metal group at omega end

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4
Q

Fat

A
  • more kcal than carbs and proteins because of higher ratio of carbon and hydrogen to oxygen
  • 9 kcal/g
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5
Q

Fatty acids vary in..(3)

A
  • length of carbon chain
  • degree of saturation
  • shape
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6
Q

Length of fatty acids (3)

A

carbon length of fatty pics 2 to 80 carbons long

  • most common 12 to 24 carbons
  • short chain, medium chain, long chain
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7
Q

Short-chain fatty acids

A

2 to 4 carbons

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8
Q

Medium-chain fatty acids

A

6 to 10 carbons

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9
Q

Long-chain fatty acids (2)

A

12 or more carbons

- most common and take longer time to digest

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10
Q

2 carbon, zero double bond

A

butyric acid

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11
Q

14 carbon, zero double bond

A

palmitic acid

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12
Q

18 carbon, 1 double bond

A

oleic acid

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13
Q

18 carbon, 2 double bond

A

linoleic acid

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14
Q

18 carbon, 3 double bond

A

alpha-linolenic acid

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15
Q

Degree of saturation of fatty acids

A

determined by whether carbons are held together by double or single bond

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16
Q

Saturated fatty acids (5)

A
  • all carbons on fatty acids are bound to hydrogen
  • no double bonds
  • solid at room temperature
  • higher melting point
  • tighter structure
17
Q

Unsaturated fatty acids (6)

A
  • carbons on fatty acids form a double bond with each other, instead of binding to hydrogen
  • Monounsaturated fatty acid (MUFA)
  • Polyunsaturated fatty acid (PUFA)
  • liquid at room temperature
  • lower melting point
  • looser structure
18
Q

Monounsaturated fatty acid (MUFA)

A

one double bond

19
Q

Polyunsaturated fatty acid (PUFA)

A

two or more double bonds

20
Q

Rancidity (3)

A
  • spoiling of fats through oxidation
  • double bonds are less stable than single bonds
  • unsaturated fats become rancid father
21
Q

How to reduce fatty acid rancidity (3)

A
  • antioxidants
  • limit exposure to oxygen, heat, and light
  • hydrogenation
22
Q

Location of double bond

A

location of first double bond from methyl (or omega) end of unsaturated fatty acids effects properties of fatty acids

23
Q

Omega-3 fatty acid

A

first double bond is between third and fourth carbons from omega end
- ex. alpha-linolenic acid

24
Q

Omega-6 fatty acid

A

first double bond is between sixth and seventh carbons from omega end
- ex. linoleic acid

25
Q

Shape of fatty acids

A

unsaturated fatty acids have two shapes based on position of hydrogen atoms around double bond
- cis form and trans form

26
Q

Cis form (2)

A

hydrogens on same side of double bond

- boat structure

27
Q

Trans form

A

hydrogens on opposite sides of double bond

28
Q

Structure of triglyceride

A

glycerol backbone + three fatty acids

29
Q

Triglycerides (3)

A
  • most common lipid
  • 95% of lipids
  • 3 fatty acids connected to glycerol backbone
30
Q

Triglycerides functions (4)

A
  • add texture to baked goods
  • make eats tender
  • preserve freshness
  • stored as adipose tissue for energy
31
Q

Phospholipids (4)

A
  • glycerol backbone, two fatty acids, a phosphate group, and nitrogen-containing compounds
  • hydrophilic tails
  • hydrophobic head
  • make up phospholipid bilayer in cell membrane