Chapter 5 - Ideal Reactors for Single Reaction Flashcards

1
Q

in this reactor, the reactants are initially charged into
a container, are well mixed, and are left to react for a certain period

A

batch reactor

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2
Q

this reactor has an unsteady-state operation where composition
changes with time; however, at any instant the composition throughout the
reactor is uniform.

A

batch reactor

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3
Q

in this reactor, characterized by the fact that the flow of fluid
through the reactor is orderly with no element of fluid overtaking or mixing with
any other element ahead or behind

A

plug flow reactor

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4
Q

in this reactor, there may be lateral mixing of
fluid but there must be no mixing or diffusion along the flow path

A

plug flow reactor

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5
Q

necessary and sufficient condition for ______ reactor is for the
residence time in the reactor to be the same for all elements of fluid

A

plug flow

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6
Q

a reactor in which the contents are well stirred and uniform throughout

A

mixed flow reactor

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7
Q

in this reactor, the exit stream from this reactor has the same composition as the fluid within
the reactor

A

mixed flow reactor

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8
Q

refers to the volume of fluid in the reactor

A

V, reactor volume

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9
Q

in this reactor, there is no fluid enters or leaves the reaction mixture
during reaction

A

batch reactor

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10
Q

the natural performance measure for a batch reactor

A

reaction time, t

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11
Q

time required to process one
reactor volume of feed measured
at specified conditions

A

space time

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12
Q

number of reactor volumes of
feed at specified conditions which
can be treated in unit time

A

space velocity

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13
Q

in this reactor, the composition of the fluid varies from point to point
along a flow path

A

plug flow reactor

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14
Q

in PFR, _____ is constant but _____ is certainly dependent on the concentration or convesion of materials

A

Fao, rA

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15
Q

in ___ rA varies while in ___ rA is constant

A

PFR, MFR

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16
Q

for systems of changing density, it is more convenient to use ___________

A

conversions

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17
Q

when the density is constant, Ea = ?

A

0

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18
Q

for systems of constant density (constant-volume batch and constant density plug flow), the performance equation are ______ and equations can be used interchangeably.

A

identical

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19
Q

for systems of changing density, there is (direct, no direct) correspondence between the batch and plug flow ewuations

A

no direct

20
Q

it is applicable to an even number of uniformly spaced intervals on the Xa axis

A

simpson’s rule

21
Q

in PFR, as space time increases, concentration of reactant ______

A

decreases

22
Q

in batch reactor, as reaction time increases, concentration of reactant __________

A

decreases

23
Q

reactors whose properties of the system do not change with time

A

steady state reactor

24
Q

reactors whose properties of the system changes with time and rate of reaction decreases with time

A

unsteady state reactor

25
Q

partially batch and partially continuous; offers good control of reaction speed because the reaction proceeds as reactants are added.

A

semi batch reactors

26
Q

which achieves higher conversion among the flow reactors for identical conditions?

A

for identical conditions, i.e for some reactor volume conversion achieved in PFR is higher than in MFR

27
Q

in this reactor, rate of reaction is independent of time and dependent on position or distance

A

PFR

28
Q

in this reactor, rate of reaction is independent of position and dependent on concentration of reactants

A

MFR

29
Q

reactor that is most suitable for very high pressure gas phase reaction

A

tubular flow reactor

30
Q

reactor that is most suitable for isothermal operation

A

back-mix reactor

31
Q

reactor for reactions where the reaction rate is fairly to extremely high, for large scale production and for good quality control

A

PFR

32
Q

a large CSTR, small CSTR and PFR of fixed volume are available. In general, how would
you arrange them for getting maximum conversion for reactions of order >1 and <1. Why

A

For n>1 arrangement is PFR followed by small CSTR followed by large CSTR to
maintain the reactant concentration as high as possible.

For n<1 arrangement is large CSTR followed by small CSTR followed by PFR.

For n=1 arrangement for first order reaction sequencing does not affect conversion. It
can be either PFR followed by MFR or MFR followed by PFR.

33
Q

reactor used to increase conversion rate by dividing the product stream and a part returned to the reactor as recycle

A

recycle reactor

34
Q

provides means for obtaining various degree of back mixing

A

recycling

35
Q

ratio of the volume fluid returned to the
reactor entrance to the volume of fluid leaving the system or reactor

A

recycle ratio

36
Q

recycle ratio can be made to vary from _____ to infinity

A

zero

37
Q

as the recycle ratio is raised, the behavior shifts from ___ (R = 0) to
______ (R = infinity)

A

PFR, MFR

38
Q

when will the recycle reactor behave like a CSTR?

A

when the recycle ratio ‘R’ becomes or tends to infinity (R=infinity), the recycle reactor
behaves like a CSTR

39
Q

what do you mean by optimum recycle operation?

A

when material is to be processed to some fixed final conversion in a recycle reactor,
there must be a particular recycle ratio ‘R’ that minimizes the reactor volume or space time.

40
Q

ratio of moles of desired product formed at
any instant to moles of reactant (A) reacted at any instant; it is a function of Ca

A

instantaneous fractional yield

41
Q

is the mean of the instantaneous fractional yields at all points within the reactor

A

overall fractional yield

42
Q

both instantaneous and overall fractional yield depend on the ______ within the reactor

A

type of flow

43
Q

is the ratio of moles of desired product to moles of undesired product

A

selectivity

44
Q

ratio of moles of product formed to moles of reactant either fed or consumed

A

yield

45
Q

how does the concentration level of reactants affect the product distribution in parallel reactions?

A

High reactant concentration favors the reaction of higher order.

Low reactant concentration favors the reaction of lower order.

The concentration level has no effect on the product distribution for reactions of the
same order