Chapter 5 Gases Flashcards
V/T=V/T
Charles’s Law
PV=PV
Boyle’s Law
V/n=V/n
AVagadro’s Law
P/T=P/T
Gay-Lussac’s Law
Ideal Gas Law
PV=nRT
mRT=MVP
DRT=MP
Value of R
.08206 atm
8.314 kPa
Dalton’s Law of Partial Pressures
Ptotal=Pa+Pb+Pc=xaPa+xbPb+xcPc
More useful: xa=na/ntotal=Pa/Ptotal
Collecting Gas over Water
Patm=Pgas+Pwv
Hydrostatic Pressure
Pressure due to water
Diffusion
Random mixing of gases
Effusion
Gas particles leave a small hole in container
Kinetic Energy Formula
KE=1/2mv^2
Same gas, different T
T1/KE1=T2/KE2
T1/v1^2=T2/v2^2
T1/(rate1)^2=T2/(rate2)^2
Different gas, same T==> Graham’s law of effusion
Ta=Tb
KEa=KEb
Ma(ratea)^2=Mb(rateb)^2
Ma(va)^2=Mb(vb)^2
Real Gas ==> Correct V & P
Compare real volume to ideal, and real pressure to ideal
Real V > Ideal V
Real P < Ideal P
— This is due to the fact that in ideal gasses it is assumed that the particles have no volume (V) and that they have no intermolecular attraction (P)