Chapter 5, Electrons and Bonding Flashcards

1
Q

What is an atomic orbital?

A

A region around the nucleus that can hold up to two electrons, with opposite spins.

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2
Q

What are the different types of orbitals?

A

s, p, d and f orbitals

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3
Q

s - how many orbitals and electrons

A

one orbital so it can hold two electrons

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4
Q

p - how many orbitals and electrons

A

has three orbitals so can hold 2*3= 6 electrons

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5
Q

d - how many orbitals and electrons

A

has 5 orbitals so can hold 2*5= 10 electrons

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6
Q

f - how many orbitals and electrons?

A

has 7 orbitals so can hold 2*7= 14 electrons

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7
Q

What are ionic compounds?

A

Oppositely charged ions held together by electrostatic attraction.

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8
Q

Features of giant ionic structures

A

regular structure
cubic shape
giant repeating pattern

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9
Q

Why do most ionic compounds dissolve in water?

A

As water molecules are polar they can attract the positive and negative ions and break up the structure.

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10
Q

Why do ionic compounds have high melting points?

A

As there are many strong electrostatic forces between oppositely charged ions. Lots of energy needed to overcome these forces.

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11
Q

What is covalent bonding?

A

The sharing of outer electrons in order for the atoms to obtain a full shell.

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12
Q

What is a dative covalent bond?

A

Where ONE atom donates 2 electrons to an atom or ion to form a bond.

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13
Q

Why do molecules have specific shapes?

A

Since bonds repel each other equally. Bonds contain electrons so they will want to be as far apart as possible.

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14
Q

What do lone pairs do in terms of shape?

A

Change the shape and bond angles. Lone pairs push bonding pairs closer together.

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15
Q

Carbon dioxide

A

BP-2 LP-0 linear 180

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16
Q

BCl3 (boron trichloride)

A

BP-3 LP-3 trigonal planar 120

17
Q

CH4 (methane)

A

BP-0 LP-0 Tetrahedral 109.5

18
Q

PCl5

A

BP-5 LP-0 trigonal bipyramidal 120 and 90 degrees

19
Q

SF6 sulfur hexafluoride

A

BP-6 LP-0 octahedral 90

20
Q

NH3 ammonia

A

BP-3 LP-1 trigonal pyramidal 107

21
Q

H20 water

A

BP-2 LP-2 non linear 104.5

22
Q

What is electronegativity?

A

The ability for an atom to attract electrons towards itself in a covalent bond.

23
Q

How do we quantify how electronegative an element is?

A

By using the Pauling scale.

24
Q

How can covalent bonds become polar?

A

If the atoms attached to it have a difference in electronegativity.

25
Q

What happens in an induced dipole dipole?

A

Electrons in an atom or molecule can move from one end to another

26
Q

Which crystal does an induced dipole-dipole force occur in?

A

Iodine

27
Q

Why are there weaker induced dipole-dipole forces in branched hydrocarbons?

A

As they can’t pack together as close. This lowers their boiling points.

28
Q
A