Chapter 5 Flashcards

You may prefer our related Brainscape-certified flashcards:
0
Q

What can slow cooling form?

A

Slow, controlled cooling can produce a single crystal, which is a highly ordered array of atoms. An example is a single crystal of silicon,used for making microchips.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
1
Q

What effect does rapid cooling have?

A

Rapid cooling tends to trap particles in an amorphous state,which resembles the disordered arrangement in a liquid. Glass is an example of an amorphous material.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

What is a polycrystalline material?

A

As a liquid cools, crystals start to form at different points within it.Each crystal grows out into the liquid, until it runs into its neighbours. The result is a patchwork of tiny crystals or grains. Where the grains meet, the interface is known as the grain boundary. Therefore a polycrystalline material consists of a number of grains, within which the structure is ordered.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

What is the eye lens composed of?

A

The eye lens is composed of a gel containing proteins, called crystallins, arranged in a regular array.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Why do people’s eye sight deteriorate?

A

The protein molecules are susceptible to oxidation damage as people age. This tends to decrease the solubility of the crystallins and degrades the crystalline structure of the lens. The result is loss in transparency.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

Why can’t we see clearly through frosted glass?

A

Frosted glass is translucent, it lets most light through. However, the frost has a rough surface and so causes the light to refract at all angles.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Why does a shattered car window appear white and opaque?

A

Is you think as the shattered glass as many little pieces of glass, where light beams into them it gets refracted several times and several directions.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

Can polymers be opaque or transparent?

A

They can be both.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

Why is polythene opaque?

A

In polythene, light is reflected and refracted at boundaries between crystalline and amorphous regions, which have different refractive indices causing it to become opaque.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

Why is Perspex transparent?

A

Perspex, which is all amorphous is transparent because the whole think is the same refractive index.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

What makes things translucent or opaque?

A

Frequent reflections and refraction so make things translucent or opaque.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

Why is glass much weaker than theoretically calculated?

A

The presence of cracks and flaws act as stress raisers, in other words, the stress around a crack can bee up to a thousand times greater than the actual applied stress. Bending the glass slightly opens up a crack which spreads throughout the material.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

Why is some glass coloured?

A

Glass is not completely colourless. If you look through a sheet of glass edge-on, it looks green or blue. Metal ions in the glass absorb light of certain wavelengths,colouring the glass.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Why are metals shiny?

A

Light penetrates almost no distance in metals. I bounces back from the surface. Free electrons in the metal absorb the light energy, and then immediately re-emit it. Metals are on sis hint for the same reason that they conduct electricity, they contain free electrons.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

How can dislocations in metals make it stronger?

A

In a metal, dislocations in the ordered crystalline structure can help to even out high stress concentrations around a crack.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

Explain the whole process from when stress is applied to glass to when the glass shatters.

A

1) When you bend glass, it becomes strained elastically. It stores strain energy.
2) At the tip of here crack, two neighbouring atoms are pulled apart, work is done in breaking this bond.
3) The next two atoms are pulled apart and so on, the crack moves through the glass like a zip being undone. The energy required to do this is known as the fracture energy.
4) Once the glass is broken it is no longer strained so it no longer stores energy. The entry has been used to break bonds and vibrate atoms.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

What is toughness?

A

The toughness of a material is measured by the energy needed to deepen and extend cracks, creating new fractured surface in the cracks. If the energy available from the stresses in the material is larger than the energy to extend the crack, the crack will propagate and the material will fail. This is why glass can break almost explosively.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
17
Q

Why are the figures very approximate for the measuring of fracture energy?

A

The energy used in fracturing a specimen varies a good deal, the new surface may vary in roughness, the number of small flying pieces can alter, and so on.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
18
Q

Explain where the stress is on material with a crack.

A

Cracks deflect tensile stress and causes the stress to be concentrated on the crack. The area is very small at the tip of a crack causing the stress to be very large there. This causes the bonds between the atoms at the bottom of crack to be highly stressed and may cause them to break.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
19
Q

Under tensile stress what happens to cracks?

A

Cracks propagate through materials.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
20
Q

Why do metals resist crack propagation?

A

Metals resist cracking because they are ductile. Cracks are broadened and blunted. They do not propagate.

Metals are tough because they are ductile.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
21
Q

Why are fibre reinforced materials tough?

A

If you think as the fibre-reinforced material as a. Soft matrix with strong thin fibres inside it. When stress is applied and a fibre breaks the stress is taken up by the other fibres. Fibre- reinforced materials use the matrix to share stress amongst many strong fibres. The matrix also protects the fibres from cracks forming. Fibre-reinforced materials are tough because cracks can’t propagate through the soft matrix.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
22
Q

How is fracture energy calculate?

A

Fracture energy= total energy used to fracture/ specimen cross- ––––––––––––––––––––––––––––––––––––––-––sectional area.

23
Q

How is tensile stress calculated?

A

Tensile stress= breaking force/ specimen cross-sectional area

24
Q

Large fracture energy=

A

=tough

25
Q

Large tensile strength=

A

=strong

26
Q

What sort of material has a high tensile stress but low fracture energy?

A

Glass

27
Q

What sort of material has a high fracture energy and high tensile strength?

A

High tensile steel

28
Q

Why is gold used for fillings?

A

Gold does not corrode or tarnish in a damp environment.

29
Q

Why are metals ductile?

A

Metals have dislocations in their structure, like little gaps where an atom could be, these dislocations means little energy is required to move the metal structure one spacing.

30
Q

What are the disadvantages of metals having dislocations?

A

Because dislocations make a metal as much as a 1000 times weaker then they would otherwise be.

31
Q

How can dislocations make metals stronger?

A

If you make many dislocations they can get entangled and prevent each other from moving.

32
Q

What is worked hardened?

A

When a metals dislocations have become entangled making the metal less ductile.

33
Q

What can happen to soft metals?

A

They can gradually deform under their own weight.

34
Q

What does alloying do to a metal?

A

Alloying disrupts the regularity of the crystal structure and makes it harder for atoms to slide past one another. The gap where the dislocation is filled up and pinned by an atom of another metal, this causes the dislocation area to slip more easily.
Alloys are generally less ductile than pure metals.

35
Q

What is a big problem with ceramics?

A

They are hard to shape due to their hardness.

36
Q

How are ceramic materials made into a desired shape?

A

Ceramic objects often made by shaping the raw materials and then heating them.

37
Q

What is sintering?

A

A laser beam shapes the ceramic material into the desired shape.

38
Q

What is a cermet?

A

A cermet is a combination of ceramic particles in a metal matrix. Such a material, can be hard, tough and strong.

39
Q

What are the properties of covalent structures?

A
  • covalent bonds share electrons between neighbouring atoms.
  • These bonds are directional, they lock atoms into place.
  • the bonds are strong and in materials such as silica the bonds make it stiff.
  • Thea toms cannot slip making materials such as silica hard and brittle.
  • atoms are linked in a rigid giant structure.
40
Q

What are the properties of ionic structures?

A
  • ionic bonds pass electrons from one another, because like charges repel and like charges attract, the charged ions hold each other in place.
  • bonds are strong and stiff.
  • ions cannot slip - hard and brittle.
  • ions are linked in a rigid giant structure.
41
Q

What are the properties of metallic structures?

A

Atoms in metals are ionised. The free electrons move between the ions. The negative charge of the electrons ‘glues’ the ions together. But the ions can easily change places.

  • metals are stiff due to strong bonds.
  • ions can slip, metals are ductile and tough.
  • ions are held together but can move.
42
Q

What is the difference between a malleable metal and a ductile metal?

A

Malleable material change shape but loose strength, ductile materials can be drawn into wires and keep strength.

43
Q

What happens when metals undergo tensile stress?

A

The gaps open up a little.

Stretching a metal stretches the bonds, but not much.

44
Q

What happens when you stretch a polymer such as polythene?

A

The chains in a polymer are folded, when under tensile stress the bonds rotate making the folded chain longer.

Stretching polythene rotates bonds.

45
Q

Why are some polymers stiffer?

A

Polymers such as polystyrene have benzene rings which stick out making chain rotations difficult
Bakelite has many cross linked chains these links prevent the chains from unfolding.

46
Q

What is vulcanisation?

A

To vulcanise a rubber, it is heated with sulphur. Cross-links are formed between the polymer chains by the sulphur atoms. The more sulphur you add the more cross links are formed and the more stiffer the rubber becomes.

47
Q

How do rubbers stretch?

A

Rubber stretches and contracts by chains uncoiling and coiling up again.

48
Q

What happens when polythene is stretched?

A

Polythene is semi-crystalline, think of polythene as cooked spaghetti. In amorphous regions the chains fold up randomly. In crystalline regions the chains line up. When stretched plastically, the chains slip past each other. More of the material has lined-up chains. More of its crystalline.

Plastic deformation in polymers is due to chains slipping past each other.

49
Q

Why does sloppy putty snap when you pull it fast but not when you pull it slow?

A

When pulling it slow you are giving the chains time to slip past each other but when you pull it fast you don’t.

50
Q

Why does the conductivity of a metal decrease as it gets warmer?

A

No more electrons become free to move. Moving electrons scatter from the vibrating lattice- so move a little less freely as the temperature rises and lattice vibrations increase.

51
Q

Why does the conductivity of a pure semiconductor increases dramatically when heated?

A

At higher temperatures, more atoms become ionised. The conductivity increases because there are more charge carriers free to move. Effects of extra lattice vibrations are much smaller.

52
Q

What is n-type silicon?

A

N- type silicon is doped with phosphorous. The phosphorous atoms ionise, giving electrons free to move throughout the material.

Phosphorous has 5 electrons in its outer shell, four are shared with silicon atoms. One becomes free to move and conduct,leaving positive P ions.

N-type= electrons conduct.

53
Q

What is p-type silicon?

A

P-type silicon is dope with boron. The boron atoms ionise, taking electrons from silicon atoms and leaving positive holes free to move throughout the material. Boron has 3 electrons in outer shell it gains one more to bond with all the surrounding silicon atoms. The electron hole left behaves like a mobile positive charge.

54
Q

What is doping .

A

Ions sprayed on silicon surface and become absorbed by the crystalline structure. Depending on the type of ions used this produces either n-type or p-type silicon.