Chapter 4 rxns in aqueous solutions Flashcards

1
Q

solution

A

homogeneous misture of 2 or more substances

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2
Q

solvent

A

substance with greatest quantity

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3
Q

solute

A

other substance, dissolved in the solvent

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4
Q

electrolyte

A

a substance whose aq solution contains ions

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5
Q

nonelectrolte

A

does no form ions in solutioon

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6
Q

solvation

A

helps stabilize the ions in solution and prevents cations and anions from recombing

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7
Q

strong electrolytes

A

those solutes that exist in solution completely or nearly completely as ions

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8
Q

weak electolytes

A

those solutes that exist in solution mostly in the form of neutral molecules with onlu a small fraction in the form of ions

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9
Q

chemical equillibrium

A

relative number of each type of ion or molecule in the rxn is constant over time

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10
Q

->

A

represents ionization of strong electrolytes.

water soluable ionic cmpds are strong electrolytes

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11
Q

precipitation rxns

A

rxns that result in the formation of an insoluable product

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12
Q

solubility

A

the amount of the substance that can be dissolved in a given amount of solvent

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13
Q

exchange (metathesis) rxns

A

rxn in which cations and anions appear to exchange partners.

have to check solubilities, for precip to occur, 1 product must be insoluable in water

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14
Q

complete ionic equation

A

all soluble strong electrolytes shown as ions

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15
Q

spectator ions

A

plays no direct role in the rxn, are exactly the same on both sides of the equation

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16
Q

net ionic equation

A

includes only ions and molecules directly invovled in the rxn. the sum of the ionic charges must be the same on both sides of the balanced net ionic equation.
steps on p 123

17
Q

acids

A

substances that ionize in aq solutions to form H ions. Proton donors

18
Q

bases

A

substances that accept (react with) H ions. produce OH- ions with dissolved in water

19
Q

neutralization rxns

A

when a soluton of an acid and a solution of a base are mixed

20
Q

salt

A

any ionic compound whose cations comes from a base

21
Q

redox rxn

A

electrons are transferred from one reactant to another

22
Q

oxidation

A

loss of elctrons, becomse + charged

23
Q

reduction

A

gain of electrons, becomes - charged

when one substance is oxidized, another must be reduced

24
Q

oxidation #s rules

A
  1. for an atom in its elemental form, the oxidation # is always 0.
  2. for any monatomic ion the oxidation # = the ionic charge
  3. nonmetals usually have negative oxidation numbers, although they can sometimes be positive.
    - the oxidation # of oxygen is usually -2. EXCEPT peroxides O2, oxidation # is -1
    - oxidation # of H is +1 when bonded to nonmetals and -1 when bonded to metals
    - F is always -1. other halogens have an oxidation number of -1 in most binary compunds. when combined with oxygen, they have positive oxidation states
  4. the sume of the oxidation # of all atoms in a neutral compound is 0. the sum of the oxidation #s in a polyatomic ion = the charge of the ion.
25
Q

activities series

A

a list of metals arranged in order of decreasing ease of oxidation .

any metal ion on the list can be oxidized by the ions of elements below it.

26
Q

concentrations

A

desgnate the amount of solute dissolveed in a given quanitity of solvent or quantity of solutoions

27
Q

Molarity, M

A

M= moles solute/volume of soln in L

28
Q

dilutoin

A

solution of lower concertrations can be obtained by adding water

M1xV1=M2V2