Chapter 4 - periodicity Flashcards
Define the term period
A horizontal row in the periodic table, they have trends in their properties
Define the term group
Vertical column of elements, similar chemical properties as they have the same outer shell electron arrangement
Describe and explain the trends in melting and boiling points of sodium to aluminium
Increases, the strength of the metallic bond increases as there’s more electrons in the mobile sea, the ions have a higher charge, the inter ionic distances are closer
Explain why the melting point of silicon is so high
Silicon is a giant macromolecule and each Si atom has 4 strong covalent bonds which require a lot of energy to overcome
Describe and explain the trend of atomic radius across period 3
Decreases as there are progressively more protons pulling on electrons in the same shell so the attraction is greater
Describe and explain the trend in first ionisation energy across a period
Increases, there are progressively more protons pulling on the same shell of outer electrons so the attraction is greater and the atomic radius is smaller so more energy is required to ionise the atom
Describe and explain the trend in first ionisation energy across a group
Decreases, there are more inner electron shells shielding the outer electrons from the +ve nuclear charge; the outer electron shells are further away so are held in more weakly, so the first ionisation energy decreases
Describe and explain the trend in atomic size across a group
Increases, theres another electron shell