Chapter 4 - Imperfections in Solids Flashcards
What is a point defect?
A defect that occurs with a singular atom
What is a linear defect?
A defect that occurs within a 1d space in the material
What is a interfacial defect?
A defect that occurs within a 2d space in the material
What is a vacancy?
A point defect where an atom is missing from where it should normally be
What is a interstitial?
An point defect where an atom places itself into a spot where normally nothing should be.
What type of metal has no defects?
None, all solids will have some type of defect, including pure metals
What is another name for a metal that is in greater amount in a solid solution?
Solvent
What is a solute in reference to alloys and solid solutions?
The metal in lesser concentration
What solid solutions are created by impurity point defects?
Substitutional and Interstitial
What do the Hume-Rothery rules describe?
The favorability of a solutes tendency to dissolve into a solvent
What is the maximum difference of atomic radius a solute and solvent can have according to Hume-Rothery, and what happens if the range is surpassed?
+-15% radius, lattice distortions form along with a new phase
What happens if the two metals have different crystal structures?
The solid solubility is non-appreciable
What is the relationship between electronegativity and solid solutions?
The more electronegative two metals are with each other, the less likely a solid solution is to form
Which metal is more likely to dissolve in another, one with higher or lower valency?
The metal with higher valency
How does a solute in an interstitial solid solution dissolve?
The impurity/solute fill the interstices between the host atoms.